Sodium isopropyl xanthate degradation by advanced oxidation processes

被引:66
作者
Cifuentes Molina, Gerardo [1 ]
Herrera Cayo, Carmen [1 ,3 ]
Siqueira Rodrigues, Marco Antonio [2 ]
Bernardes, Andrea Moura [3 ]
机构
[1] Univ Santiago Chile, Fac Ingn, Dept Ing, Estn Cent, Santiago, Chile
[2] ICET, Ctr Univ Feevale, BR-93352000 Novo Hamburg, RS, Brazil
[3] Univ Fed Rio Grande do Sul, PPGE3M, BR-91501970 Porto Alegre, RS, Brazil
关键词
Sodium isopropyl xanthate; Advanced oxidation process; Copper mineral flotation; UV photolysis; Electrolysis; Photoelectrooxidation; INORGANIC-COMPOUNDS; RATE CONSTANTS; WASTE-WATER; OZONE; REAGENTS; REUSE; ACID;
D O I
10.1016/j.mineng.2012.12.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper presents the results obtained by different oxidative processes when an aqueous solution containing sodium isopropyl xanthate is treated; this reagent is used in the flotation of copper minerals. The advanced oxidation processes used are UV photolysis, direct electrolysis and photoelectrooxidation. The solutions used containing sodium isopropyl xanthate were adjusted to the following concentrations: 6, 8, 10, 25 and 40 mg L-1. The results show that the three oxidation processes proved to be suitable for the destruction of xanthate, with the following maximum destruction efficiencies: 76% for electrolysis, 95% for UV photolysis and 99% for photoelectrooxidation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:88 / 93
页数:6
相关论文
共 29 条
[1]   Ozone generation by silent electric discharge and its application in tertiary treatment of tannery effluent [J].
Balakrishnan, PA ;
Arunagiri, A ;
Rao, PG .
JOURNAL OF ELECTROSTATICS, 2002, 56 (01) :77-86
[2]  
Bertazzoli R, 2002, QUIM NOVA, V25, P477, DOI 10.1590/S0100-40422002000300022
[3]  
Bolton J.R., 1995, J ADV OXIDATION TECH
[4]   In-line TiO2-assisted photodigestion of organic matter in aqueous solution for voltammetric flow analysis of heavy metals in water samples [J].
Cavicchioli, A ;
Gutz, IGR .
ANALYTICA CHIMICA ACTA, 2001, 445 (02) :127-138
[5]   Primary biodegradation of sulfide mineral flotation collectors [J].
Chen, Shaohua ;
Gong, Wenqi ;
Mei, Guangjun ;
Zhou, Qi ;
Bai, Cuiping ;
Xu, Nian .
MINERALS ENGINEERING, 2011, 24 (08) :953-955
[6]   Continuous removal of ore floatation reagents by an anaerobic-aerobic biological filter [J].
Cheng, Huang ;
Lin, Hai ;
Huo, Hanxin ;
Dong, Yingbo ;
Xue, Qiuyu ;
Cao, Lixia .
BIORESOURCE TECHNOLOGY, 2012, 114 :255-261
[7]   Studies on biodegradation of organic flotation collectors using Bacillus polymyxa [J].
Chockalingam, E ;
Subramanian, S ;
Natarajan, KA .
HYDROMETALLURGY, 2003, 71 (1-2) :249-256
[8]  
Cifuentes G., 2000, DEGRADACION FOTOQUIM
[9]  
Cifuentes G., 1994, 49 C AN ABM PAL CONV
[10]  
Foti G., 1997, Curr. Top. Electrochem, V5, P71