Syntheses and Characterization of 1,1′-Bis(3-Pyridylethynyl)Ferrocene and 1,1′-Bis(4-Pyridylethynyl)Ferrocene

被引：8

作者：

Lindner, Ekkehard ^{[1
]}

Zong, Ruifa ^{[1
]}

Eichele, Klaus ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 169卷 / 01期

关键词：

disubsitituted; ferrocene; ethynyl; pyridine;

D O I：

10.1080/10426500108546628

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel disubstituted ferrocene, 1,1 -bis(3-pyridylethynyl)ferrocene 1 and 1, 1-bis(4-pyridylethynyl) ferrocene 2, were synthesized and fully characterized by elemental analysis, H-1 NMR, C-13 NMR, IR, and X-ray crystallography. Compound 1crystallizes in monoclinic, space group Cc, a=17.26 angstrom, b=9.77 angstrom, c=10.85 angstrom, beta=105.45; R-1 =0.0399, wR(2)=0.1077, GooF=1.023. The two arms of the ferrocene are parallel, which will play an important role both in the coordination chemistry and electronic communication of the ferrocene.

引用

页码：219 / 222

页数：4

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