Novel columnar mesogen with octupolar optical nonlinearities: synthesis, mesogenic behavior and multiphoton-fluorescence-free hyperpolarizabilities of subphthalocyanines with long aliphatic chains

被引：74

作者：

Kang, SH

Kang, YS

Zin, WC

Olbrechts, G

Wostyn, K

Clays, K

Persoons, A

Kim, K

机构：

[1] Univ Louvain, Dept Chem, Ctr Res Mol Elect & Photon, Lab Chem & Biol Dynam, B-3001 Louvain, Belgium

[2] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, Pohang 790784, South Korea

[3] Pohang Univ Sci & Technol, Dept Chem, Natl Creat Res Initiat Smart Supramol, Pohang 790784, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904254g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel subphthalocyanines with long thioalkyl chains exhibit hexagonal columnar mesophases at room temperature; their inherent first hyperpolarizability values (beta) measured by hyper-Rayleigh scattering (HRS) with fluorescence suppression are (189 +/- 30) x 10(-30) esu at 1300 nm.

引用

收藏

页码：1661 / 1662

页数：2

相关论文

共 24 条

[1] DISCOTIC LIQUID-CRYSTALS - A BRIEF REVIEW [J].

CHANDRASEKHAR, S .

LIQUID CRYSTALS, 1993, 14 (01) :3-14

[2] Enhancement of the molecular hyperpolarizability by a supramolecular amylose-dye inclusion complex, studied by hyper-Rayleigh scattering with fluorescence suppression [J].

Clays, K ;

Olbrechts, G ;

Munters, T ;

Persoons, A ;

Kim, OK ;

Choi, LS .

CHEMICAL PHYSICS LETTERS, 1998, 293 (5-6) :337-342

[3] NEW BOWL-SHAPED COLUMNAR LIQUID-CRYSTALS [J].

COMETTI, G ;

DALCANALE, E ;

DUVOSEL, A ;

LEVELUT, AM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) :163-165

[4] Synthesis and nonlinear optical, photophysical, and electrochemical properties of subphthalocyanines [J].

del Rey, B ;

Keller, U ;

Torres, T ;

Rojo, G ;

Agulló-López, F ;

Nonell, S ;

Martí, C ;

Brasselet, S ;

Ledoux, I ;

Zyss, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (49) :12808-12817

[5]

Geyer M, 1996, SYNTHESIS-STUTTGART, P1139

[6] Hyper-Rayleigh Scattering in isotropic solution [J].

Hendrickx, E ;

Clays, K ;

Persoons, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (10) :675-683

[7] Trinuclear gold(I) pyrazolate complexes exhibiting hexagonal columnar mesophases with only three side chains [J].

Kim, SJ ;

Kang, SH ;

Park, KM ;

Kim, H ;

Zin, WC ;

Choi, MG ;

Kim, K .

CHEMISTRY OF MATERIALS, 1998, 10 (07) :1889-1893

[8] NEW ROUTE TO UNSYMMETRICAL PHTHALOCYANINE ANALOGS BY THE USE OF STRUCTURALLY DISTORTED SUBPHTHALOCYANINES [J].

KOBAYASHI, N ;

KONDO, R ;

NAKAJIMA, S ;

OSA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (26) :9640-9641

[9]

KOBAYASHI N, IN PRESS J PORPHYRIY

[10] HIGH-DENSITY NANOSECOND CHARGE TRAPPING IN THIN-FILMS OF THE PHOTOCONDUCTOR ZNODEP [J].

LIU, CY ;

PAN, HI ;

FOX, MA ;

BARD, AJ .

SCIENCE, 1993, 261 (5123) :897-899