An Antilock Molecular Braking System

被引:24
|
作者
Sun, Wei-Ting [2 ]
Huang, Shou-Ling [2 ]
Yao, Hsuan-Hsiao [1 ]
Chen, I-Chia [1 ]
Lin, Ying-Chih [2 ]
Yang, Jye-Shane [2 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
关键词
SENSITIZED SOLAR-CELLS; ELECTRON-TRANSFER; TRANS-STILBENE; CIS-STILBENE; LIGHT; FLUORESCENCE; PHOTOISOMERIZATION; MACHINES; MOTIONS;
D O I
10.1021/ol3018193
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A light-driven molecular brake displaying an antilock function is constructed by introducing a nonradiative photoinduced electron transfer (PET) decay channel to compete with the trans (brake-off) -> cis (brake-on) photoisomerization. A fast release of the brake can be achieved by deactivating the PET process through addition of protons. The cycle of irradiation-protonation-irradiation-deprotonation conducts the brake function and mimics the antilock braking system (ABS) of vehicles.
引用
收藏
页码:4154 / 4157
页数:4
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