Structure stability of metal-organic framework MIL-53 (Al) in aqueous solutions

被引：169

作者：

Qian, Xukun ^{[1
]}

Yadian, Boluo ^{[1
]}

Wu, Renbing ^{[2
]}

Long, Yi ^{[1
]}

Zhou, Kun ^{[2
]}

Zhu, Bin ^{[3
]}

Huang, Yizhong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore

[3] Royal Inst Technol KTH, Dept Energy Technol, SE-10044 Stockholm, Sweden

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 36期

关键词：

Metal-organic frameworks; Structure stability; Aqueous solution; MIL-53 (Al); HYDROGEN STORAGE PROPERTIES; COORDINATION POLYMERS; DRUG-DELIVERY; SURFACE-AREA; WATER; ADSORPTION; SEPARATION; CO2; TEMPERATURE; HYDRATION;

D O I：

10.1016/j.ijhydene.2013.07.054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structural stability of MIL-53 (Al) in different pH aqueous solutions from room temperature to 100 degrees C has been investigated. Experimental results show MIL-53 (Al) is stable and highly resistant to hydrolysis in neutral and acidic solutions. It can retain its crystallinity and permanent porosity without structural collapse. The good structure stability of MIL-53 (Al) to aqueous solutions is quite unusual among the MOFs. The nitrogen adsorption for the soaked frameworks show a typical type I isotherm. In basic aqueous solution, MIL-53 (Al) undergoes structure transformation. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：16710 / 16715

页数：6

共 42 条

[1] Adsorption of CO2 and CH4 on a magnesium-based metal organic framework [J].

Bao, Zongbi ;

Yu, Liang ;

Ren, Qilong ;

Lu, Xiuyang ;

Deng, Shuguang .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 353 (02) :549-556

[2]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[3]

2-Y

[4] A microporous metal-organic framework with high stability for GC separation of alcohols from water [J].

Borjigin, Tsolmon ;

Sun, Fuxing ;

Zhang, Jinlei ;

Cai, Kun ;

Ren, Hao ;

Zhu, Guangshan .

CHEMICAL COMMUNICATIONS, 2012, 48 (61) :7613-7615

[5] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[6] Hydrogen storage in water-stable metal-organic frameworks incorporating 1,3-and 1,4-benzenedipyrazolate [J].

Choi, Hye Jin ;

Dinca, Mircea ;

Dailly, Anne ;

Long, Jeffrey R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (01) :117-123

[7] Enhancement of hydrogen adsorption by alkali-metal cation doping of metal-organic framework-5 [J].

Chu, Chun-Lin ;

Chen, Jiann-Ruey ;

Lee, Tsung-Yu .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (08) :6721-6726

[8] High thermal and chemical stability in pyrazolate-bridged metal-organic frameworks with exposed metal sites [J].

Colombo, Valentina ;

Galli, Simona ;

Choi, Hye Jin ;

Han, Ggoch Ddeul ;

Maspero, Angelo ;

Palmisano, Giovanni ;

Masciocchi, Norberto ;

Long, Jeffrey R. .

CHEMICAL SCIENCE, 2011, 2 (07) :1311-1319

[9] Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water [J].

Cychosz, Katie A. ;

Matzger, Adam J. .

LANGMUIR, 2010, 26 (22) :17198-17202

[10] How Can a Hydrophobic MOF be Water-Unstable? Insight into the Hydration Mechanism of IRMOFs [J].

De Toni, Marta ;

Jonchiere, Romain ;

Pullumbi, Pluton ;

Coudert, Francois-Xavier ;

Fuchs, Alain H. .

CHEMPHYSCHEM, 2012, 13 (15) :3497-3503

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