Conversion of xylan, D-xylose and lignocellulosic biomass into furfural using AlCl3 as catalyst in ionic liquid

被引：157

作者：

Zhang, Luxin ^{[1
]}

Yu, Hongbing ^{[1
]}

Wang, Pan ^{[2
]}

Dong, Heng ^{[1
]}

Peng, Xinhong ^{[1
]}

机构：

[1] Nankai Univ, Coll Environm Sci & Engn, Tianjin 300071, Peoples R China

[2] Beijing Technol & Business Univ, Sch Food & Chem Engn, Beijing 102488, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2013年 / 130卷

关键词：

Furfural; Lignocellulosic biomass; Xylan; D-Xylose; Ionic liquid; INORGANIC SALTS; CORN STOVER; ACID; DEHYDRATION; HEMICELLULOSE; SUGARS; STRAW; WATER;

D O I：

10.1016/j.biortech.2012.12.018

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

to define a new green catalytic pathway for the production of furfural, the catalyzed conversion of xylan into furfural in 1-butyl-3-methylimidazolium chloride was studied by using mineral acids and metal chlorides as catalysts under microwave irradiation. Amongst these catalysts, AlCl3 resulted in the highest furfural yield of 84.8% at 170 degrees C for 10 s. The effect of AlCl3 on the conversion efficiency of D-xylose and untreated lignocellulosic biomass was also investigated, the yields of furfural from corncob, grass and pine wood catalyzed by AlCl3 in [BMIM]Cl were in the range of 16-33%. [BMIM]Cl and AlCl3 could be recycled for four runs with stable catalytic activity. AlCl3 is less corrosive than mineral acids, and the use of ionic liquid as reaction medium will no longer generate toxic wastewater, thus this reaction system is more ecologically viable. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：110 / 116

页数：7

共 35 条

[1] Pore size tuning of functionalized SBA-15 catalysts for the selective production of furfural from xylose [J].

Agirrezabal-Telleria, I. ;

Requies, J. ;

Gueemez, M. B. ;

Arias, P. L. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 115 :169-178

[2] Furfural production from xylose using sulfonic ion-exchange resins (Amberlyst) and simultaneous stripping with nitrogen [J].

Agirrezabal-Telleria, I. ;

Larreategui, A. ;

Requies, J. ;

Gueemez, M. B. ;

Arias, P. L. .

BIORESOURCE TECHNOLOGY, 2011, 102 (16) :7478-7485

[3] KINETIC-STUDIES OF THE REACTIONS OF KETOSES AND ALDOSES IN WATER AT HIGH-TEMPERATURE .3. MECHANISM OF FORMATION OF 2-FURALDEHYDE FROM D-XYLOSE [J].

ANTAL, MJ ;

LEESOMBOON, T ;

MOK, WS ;

RICHARDS, GN .

CARBOHYDRATE RESEARCH, 1991, 217 :71-85

[4] Efficient microwave-assisted production of furfural from C5 sugars in aqueous media catalysed by Bronsted acidic ionic liquids [J].

Carlos Serrano-Ruiz, Juan ;

Campelo, Juan M. ;

Francavilla, Matteo ;

Romero, Antonio A. ;

Luque, Rafael ;

Menendez-Vazquez, Carmen ;

Garcia, Ana B. ;

Garcia-Suarez, Eduardo J. .

CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (09) :1828-1832

[5] Catalytic conversion of sugarcane bagasse, rice husk and corncob in the presence of TiO2, ZrO2 and mixed-oxide TiO2-ZrO2 under hot compressed water (HCW) condition [J].

Chareonlimkun, A. ;

Champreda, V. ;

Shotipruk, A. ;

Laosiripojana, N. .

BIORESOURCE TECHNOLOGY, 2010, 101 (11) :4179-4186

[6] Acidic cesium salts of 12-tungstophosphoric acid as catalysts for the dehydration of xylose into furfural [J].

Dias, Ana S. ;

Lima, Sergio ;

Pillinger, Martyn ;

Valente, Anabela A. .

CARBOHYDRATE RESEARCH, 2006, 341 (18) :2946-2953

[7]

Dunlop AP, 1953, ACS MONOGRAPH SERIES

[8]

Gravitis Janis., 2001, Chemicals and Materials from Renewable Resources, V784, P110

[9]

Hayes BL, 2004, ALDRICHIM ACTA, V37, P66

[10] Flexible coordination environments of lanthanide complexes grown from chloride-based ionic liquids [J].

Hines, C. Corey ;

Cordes, David B. ;

Griffin, Scott T. ;

Watts, Savannah I. ;

Cocalia, Violina A. ;

Rogers, Robin D. .

NEW JOURNAL OF CHEMISTRY, 2008, 32 (05) :872-877

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