Metal organic framework adsorbent for biogas upgrading

被引:184
作者
Cavenati, Simone [1 ]
Grande, Carlos A. [1 ]
Rodrigues, Alirio E. [1 ]
机构
[1] Univ Porto, Fac Engn, Lab Separat & React Engn, Associate Lab LSRE LCM,Dept Chem Engn, P-4200465 Oporto, Portugal
关键词
D O I
10.1021/ie8005269
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The discovery of new materials with enhanced selectivity or capacity will boost adsorption applications, especially for environmental control. In particular, it was mentioned that metal-organic frameworks (MOF) with different tailored properties may be prepared for desired separations. To promote industrial application of MOF materials, up-scaling and process design still must be completely developed. In this work, we report adsorption equilibrium data of methane and carbon dioxide on Cu-MOF extrudates. The most important properties observed are the high-capacity for CO(2) and the small nonlinearity of the isotherms. In this context, this adsorbent can be used for biogas upgrading to produce biomethane and reduce fossil-fuel CO(2).
引用
收藏
页码:6333 / 6335
页数:3
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