Metal organic framework adsorbent for biogas upgrading

被引:184
作者
Cavenati, Simone [1 ]
Grande, Carlos A. [1 ]
Rodrigues, Alirio E. [1 ]
机构
[1] Univ Porto, Fac Engn, Lab Separat & React Engn, Associate Lab LSRE LCM,Dept Chem Engn, P-4200465 Oporto, Portugal
关键词
D O I
10.1021/ie8005269
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The discovery of new materials with enhanced selectivity or capacity will boost adsorption applications, especially for environmental control. In particular, it was mentioned that metal-organic frameworks (MOF) with different tailored properties may be prepared for desired separations. To promote industrial application of MOF materials, up-scaling and process design still must be completely developed. In this work, we report adsorption equilibrium data of methane and carbon dioxide on Cu-MOF extrudates. The most important properties observed are the high-capacity for CO(2) and the small nonlinearity of the isotherms. In this context, this adsorbent can be used for biogas upgrading to produce biomethane and reduce fossil-fuel CO(2).
引用
收藏
页码:6333 / 6335
页数:3
相关论文
共 17 条
  • [1] Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures
    Cavenati, S
    Grande, CA
    Rodrigues, AE
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) : 1095 - 1101
  • [2] Design of new materials for methane storage
    Düren, T
    Sarkisov, L
    Yaghi, OM
    Snurr, RQ
    [J]. LANGMUIR, 2004, 20 (07) : 2683 - 2689
  • [3] Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic frameworks
    Furukawa, Hiroyasu
    Miller, Michael A.
    Yaghi, Omar M.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3197 - 3204
  • [4] Layered vacuum pressure-swing adsorption for biogas upgrading
    Grande, Carlos A.
    Rodrigues, Alirio E.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (23) : 7844 - 7848
  • [5] Biogas to fuel by vacuum pressure swing adsorption - I. Behavior of equilibrium and kinetic-based adsorbents
    Grande, Carlos A.
    Rodrigues, Alirio E.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (13) : 4595 - 4605
  • [6] Hagen M., 2001, Adding gas from biomass to the gas grid
  • [7] High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons
    Himeno, S
    Komatsu, T
    Fujita, S
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (02) : 369 - 376
  • [8] Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
    Kaye, Steven S.
    Dailly, Anne
    Yaghi, Omar M.
    Long, Jeffrey R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) : 14176 - +
  • [9] Kinetic separation of landfill gas by a two-bed pressure swing adsorption process packed with carbon molecular sieve: Nonisothermal operation
    Kim, Min-Bae
    Bae, Youn-Sang
    Choi, Dae-Ki
    Lee, Chang-Ha
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (14) : 5050 - 5058
  • [10] Landfill gas: From rubbish to resource
    Knaebel, KS
    Reinhold, HE
    [J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2003, 9 (01): : 87 - 94