Synthesis of micron-SiO2@nano-Ag particles and their catalytic performance in 4-nitrophenol reduction

被引:113
作者
Wang, Man [1 ]
Tian, Di [1 ]
Tian, Panpan [1 ]
Yuan, Liangjie [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
关键词
Micron-SiO2@nano-Ag particles; 4-Nitrophenol reduction; Catalytic activity; SILVER NANOPARTICLES; SILICA SPHERES; DEPOSITION; NANOSHELLS;
D O I
10.1016/j.apsusc.2013.06.120
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ag nanoparticles (Ag NPs) were deposited on the surface of micron silica spheres. The structure of the composite was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX), transmission electron microscope (TEM) and inductively coupled plasma-atomic emission spectrometry (ICP-AES) method. The as-prepared micron-SiO2@nano-Ag particles were used as a catalyst in the borohydride reduction reaction of 4-nitrophenol (4-NP), which was detected by UV-vis absorption spectroscopy. The result showed that the composite particles presented a comparable catalytic activity with that of spherical silver nanoparticles. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:389 / 395
页数:7
相关论文
共 19 条
[1]   Large scale and environmentally friendly preparation of micro-submicron spherical silica and their surface effect in resin materials [J].
Ai, Changchun ;
Xiao, Yong ;
Wen, Wen ;
Yuan, Liangjie .
POWDER TECHNOLOGY, 2011, 210 (03) :323-327
[2]   Synthesis of worm like silver nanoparticles in methyl cellulose polymeric matrix and its catalytic activity [J].
Bhui, Dipak Kumar ;
Misra, Ajay .
CARBOHYDRATE POLYMERS, 2012, 89 (03) :830-835
[3]   A general method for synthesis continuous silver nanoshells on dielectric colloids [J].
Chen, Dong ;
Liu, Hui-Yu ;
Liu, Jian-Shu ;
Ren, Xiang-Lin ;
Meng, Xian-Wei ;
Wu, Wei ;
Tang, Fang-Qiong .
THIN SOLID FILMS, 2008, 516 (18) :6371-6376
[4]   Novel method to fabricate SiO2/Ag composite spheres and their catalytic, surface-enhanced Raman scattering properties [J].
Deng, Ziwei ;
Chen, Min ;
Wu, Limin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (31) :11692-11698
[5]  
El-Nour K.M. M. Abou., 2010, Arab. J. Chem, V3, P135, DOI DOI 10.1016/J.ARABJC.2010.04.008
[6]   Direct formation of silver nanoparticles in cuttlebone-derived organic matrix for catalytic applications [J].
Jia, Xueping ;
Ma, Xiaoyuan ;
Wei, Dongwei ;
Dong, Jian ;
Qian, Weiping .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 330 (2-3) :234-240
[7]   Facile route to silver submicron-sized particles and their catalytic activity towards 4-nitrophenol reduction [J].
Jiang, Deli ;
Xie, Jimin ;
Chen, Min ;
Li, Di ;
Zhu, Jianjun ;
Qin, Huiru .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (05) :1975-1979
[8]   Seed-mediated growth technique for the preparation of a silver nanoshell on a silica sphere [J].
Jiang, ZJ ;
Liu, CY .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (45) :12411-12415
[9]   Deposition of sliver nanoparticles on silica spheres by pretreatment steps in electroless plating [J].
Kobayashi, Y ;
Salgueiriño-Maceira, V ;
Liz-Marzán, LM .
CHEMISTRY OF MATERIALS, 2001, 13 (05) :1630-1633
[10]   Synthesis of graphene oxide sheets decorated by silver nanoparticles in organic phase and their catalytic activity [J].
Mao, Aiqin ;
Zhang, Danhui ;
Jin, Xia ;
Gu, Xiaolong ;
Wei, Xiaoqing ;
Yang, Guojing ;
Liu, Xiaoheng .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2012, 73 (08) :982-986