Solubility of anthracene in binary toluene plus alcohol solvent mixtures at 298.15K

被引:2
|
作者
Dabadge, Nishu [1 ]
Tian, Amy [1 ]
Wilson, Anastasia [1 ]
Barrera, Maribel [1 ]
Payne, Megan [1 ]
Sanchez, Erika [1 ]
Sanchez, Troy [1 ]
Acree, William E., Jr. [1 ]
机构
[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA
关键词
anthracene solubilities; toluene; alcohols; mathematical representation; binary solvents; CYCLOHEXANE; HEPTANE; PROPANOL+1-PENTANOL;
D O I
10.1080/00319104.2012.723710
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experimental solubilities are reported for anthracene in eight binary toluene + alcohol solvent mixtures at 298.15 K. The alcohol solvents studied were 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 2-propanol, 2-butanol, 2-methyl-1-propanol and 3-methyl-1-butanol. Results of these measurements were used to test a mathematical representation based on the combined nearly ideal binary solvent (NIBS)/Redlich-Kister equation. For the eight systems studied, the combined NIBS/Redlich-Kister equation was found to accurately describe the experimental data, with an average absolute deviation between the measured and back-calculated values being approximately +/- 0.4%.
引用
收藏
页码:812 / 818
页数:7
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