Nonlinear viscoelastic-degradation model for polymeric based materials

This study presents a phenomenological constitutive model for describing response of solid-like viscoelastic polymers undergoing degradation. The model is expressed in terms of recoverable and irrecoverable time-dependent parts. We use a time-integral function with a nonlinear integrand for the recoverable part and another time-integral function is used for the irrecoverable part, which is associated with the degradation evolution in the materials. Here, the degradation is attributed to the secondary and tertiary creep stages. An 'internal clock' concept in viscoelastic materials is used to incorporate the accelerated failure in the materials at high stress levels. We ignore the effect of heat generation due to the dissipation of energy and possible healing in predicting the long-term and failure response of the polymeric materials. Experimental data on polymer composites reported by Drozdov (2011) were used to characterize the material parameters and validate the constitutive model. The model is shown capable of predicting response of the polymer composites under various loading histories: creep, relaxation, ramp loading with a constant rate, and cyclic loadings. We observed that the failure time and number of cycles to failure during cyclic loadings are correlated to the duration of loading and magnitude of the prescribed mechanical loads. A scalar degradation variable is also introduced in order to determine the severity of the degradation in the materials, which is useful to predict the lifetime of the structures subject to various loading histories during the structural design stage. (C) 2013 Elsevier Ltd. All rights reserved.