Nanohybrids composed of quantum dots and cytochrome P450 as photocatalysts

被引：107
作者：
Ipe, BI
Niemeyer, CM
机构：
[1] Univ Dortmund, Fachbereich Chem, D-44227 Dortmund, Germany
[2] ISAS, Inst Analyt Sci, D-44139 Dortmund, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期
关键词：
nanostructures; photochemistry; quantum dots; radicals;
D O I：
10.1002/anie.200503084
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Synthesis with light: CdS quantum dots (QDs) generate superoxide and hydroxyl radicals upon UV irradiation in aqueous solution. The radicals are used for activating P450BSβ enzymes attached at the QD surface, effecting the catalytic transformation of myristic acid into α- and β-hydroxymyristic acid (see picture, R = (CH 2)10CH3). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：504 / 507
页数：4
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