Active pseudo-multilayered films from polycaprolactone and starch based matrix for food-packaging applications

被引:53
作者
Alix, Sebastien [1 ]
Mahieu, Angelique [1 ]
Terrie, Caroline [1 ]
Soulestin, Jeremie [2 ]
Gerault, Eloise [3 ]
Feuilloley, Marc G. J. [3 ]
Gattin, Richard [1 ]
Edon, Vincent [4 ]
Ait-Younes, Tarik [4 ]
Leblanc, Nathalie [1 ]
机构
[1] Esitpa, Equipe LGMA, Unite AGRITERR, F-76134 Mont St Aignan, France
[2] Ecole Mines Douai, Dept Polymers & Composites Technol & Mech Engn, F-59500 Douai, France
[3] Univ Rouen, EA 4312, Lab Microbiol Signaux & Environm, F-27000 Evreux, France
[4] CRT Anal & Surfaces, Lab Eric Beucher, F-27100 Val De Reuil, France
关键词
Biopolymer; Blend; Antimicrobial activity; Chitosan; Flour; Scavenger; BIODEGRADABLE POLYMERS; PLASTICIZED STARCH; WATER SORPTION; BLENDS; BIOCOMPOSITES; DEFORMATION; FLUORESCENS; CHITOSAN; KINETICS; FLAX;
D O I
10.1016/j.eurpolymj.2013.03.016
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Within the recent years, researches dealing with the applications of intelligent and active packaging for food applications have taken a great importance. Intelligent packaging-systems are used to inform and advertise the consumers by giving information on the food quality during transport and storage. Active packaging-systems have also acquired new functions as antimicrobials and/or oxygen or water scavenging activities by incorporating active molecules. The aim of these packaging is to maintain or extend the quality and shelf-life of the food element. The application of this strategy, concerning bio-sourced packaging, is recent. In this work, polycaprolactones were blended in a starch based matrix to improve the suitability for contact with food of the packaging and to obtain a modulated water-scavenger effect. The migration of PCL in the pseudo-multilayered and multilayered films was investigated by FT-IR. Moreover, chitosan was included in the formulation to reduce the bacterial adhesion potential on the packaging. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1234 / 1242
页数:9
相关论文
共 46 条
[11]   SAFETY ASSESSMENT OF POLYLACTIDE (PLA) FOR USE AS A FOOD-CONTACT POLYMER [J].
CONN, RE ;
KOLSTAD, JJ ;
BORZELLECA, JF ;
DIXLER, DS ;
FILER, LJ ;
LADU, BN ;
PARIZA, MW .
FOOD AND CHEMICAL TOXICOLOGY, 1995, 33 (04) :273-283
[12]  
Dainelli D., 2008, Trends in Food Sci. Tech, V19, pS103, DOI [10.1016/j.tifs.2008.09.011, DOI 10.1016/J.TIFS.2008.09.011]
[13]   Perspectives for chitosan based antimicrobial films in food applications [J].
Dutta, P. K. ;
Tripathi, Shipra ;
Mehrotra, G. K. ;
Dutta, Joydeep .
FOOD CHEMISTRY, 2009, 114 (04) :1173-1182
[14]   Thermodynamics of high polymer solutions [J].
Flory, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1942, 10 (01) :51-61
[15]   THERMODYNAMICS OF DILUTE SOLUTIONS OF HIGH POLYMERS [J].
FLORY, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1945, 13 (11) :453-465
[16]   Thermodynamics of high polymer solutions [J].
Flory, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (08) :660-661
[17]   Experimental characterization of deformation damage in solid polymers under tension, and its interrelation with necking [J].
G'Sell, C ;
Hiver, JM ;
Dahoun, A .
INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES, 2002, 39 (13-14) :3857-3872
[18]   Plasticisation and mobility in starch-sorbitol films [J].
Gaudin, S ;
Lourdin, D ;
Le Botlan, D ;
Ilari, JL ;
Colonna, P .
JOURNAL OF CEREAL SCIENCE, 1999, 29 (03) :273-284
[19]   Analysis of water binding in starch plasticized films [J].
Godbillot, L ;
Dole, P ;
Joly, C ;
Rogé, B ;
Mathlouthi, M .
FOOD CHEMISTRY, 2006, 96 (03) :380-386
[20]   Kinetics of water sorption in flax and PET fibers [J].
Gouanve, F. ;
Marais, S. ;
Bessadok, A. ;
Langevin, D. ;
Metayer, M. .
EUROPEAN POLYMER JOURNAL, 2007, 43 (02) :586-598