Copper(I) Iodide Catalyzed Synthesis of Thiophosphates by Coupling of H-Phosphonates with Benzenethiols

被引：59

作者：

Kaboudin, Babak ^{[1
]}

Abedi, Yaghoub ^{[1
]}

Kato, Jun-ya ^{[2
]}

Yokomatsu, Tsutomu ^{[2
]}

机构：

[1] Inst Adv Studies Basic Sci, Dept Chem, Zanjan 4513766731, Iran

[2] Tokyo Univ Pharm & Life Sci, Sch Pharm, Hachioji, Tokyo 1920392, Japan

来源：

SYNTHESIS-STUTTGART | 2013年 / 45卷 / 16期

关键词：

thiophosphates; copper iodide; thiols; H-phosphonates; coupling; ONE-POT SYNTHESIS; ORGANOPHOSPHORUS COMPOUNDS; BETA-CYCLODEXTRIN; DIETHYL PHOSPHITE; VERSATILE REAGENT; GENERAL-METHOD; S-ARYL; EFFICIENT; ACIDS; SULFUR;

D O I：

10.1055/s-0033-1339186

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, efficient, and new method has been developed for the preparation of thiophosphates from benzenethiols. The method involves copper(I) iodide catalyzed coupling of thiols with H-phosphonates in the presence of triethylamine. The reaction proceeds effectively to afford the corresponding thiophosphates in moderate to good yields via an aerobic dehydrogenative coupling of H-phosphonates with benzenethiols. This method is easy, rapid, and good-yielding for the synthesis of thiophosphates from benzenethiols.

引用

页码：2323 / 2327

页数：5

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