Novel triarylamine-based aromatic polyamides bearing secondary amines: synthesis and redox potential inversion characteristics induced by pyridines

被引：9

作者：

Yen, Hung-Ju ^{[1
,3
]}

Lin, Jhe-Huang ^{[1
]}

Su, Yuhlong Oliver ^{[2
]}

Liou, Guey-Sheng ^{[1
]}

机构：

[1] Natl Taiwan Univ, Inst Polymer Sci & Engn, 1 Roosevelt Rd,4th Sec, Taipei 10617, Taiwan

[2] Natl Chi Nan Univ, Dept Appl Chem, Nantou 54561, Taiwan

[3] Los Alamos Natl Lab, Div Chem, Phys Chem & Appl Spect, Los Alamos, NM 87545 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2016年 / 4卷 / 43期

关键词：

DEPENDENT RECEPTORS; HYDROGEN; ELECTROCHEMISTRY; REDUCTION; ARYLUREAS; QUINONES;

D O I：

10.1039/c6tc03409h

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Novel triarylamine-based aramids with secondary amine moieties are prepared and utilized as electrochemical detectors for pyridines. Their electrochemical behavior with different pyridines was investigated in order to demonstrate the ionic hydrogen bonding interaction of the secondary amine with the pyridines, resulting in obvious potential inversion which is also supported by in situ absorption measurements.

引用

页码：10381 / 10385

页数：5

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