Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones

被引：134

作者：

Gyoemoere, Adam ^{[1
]}

Bakos, Maria ^{[1
]}

Foeldes, Tamas ^{[1
]}

Papai, Imre ^{[1
]}

Domjan, Attila ^{[1
]}

Soos, Tibor ^{[1
]}

机构：

[1] Hungarian Acad Sci, Res Ctr Nat Sci, Inst Organ Chem, H-1117 Budapest, Hungary

来源：

ACS CATALYSIS | 2015年 / 5卷 / 09期

基金：

匈牙利科学研究基金会;

关键词：

frustrated Lewis pair; hydrogenation; catalysis; moisture tolerant; carbonyl; METAL-FREE HYDROGENATION; INITIO MOLECULAR-DYNAMICS; H BOND ACTIVATION; DIHYDROGEN ACTIVATION; CARBONYL-COMPOUNDS; B(C6F5)(3); CHEMISTRY; MECHANISM; ACIDITY; ETHERS;

D O I：

10.1021/acscatal.5b01299

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, we report on the development of a bench-stable borane for frustrated Lewis pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of structural and electronic parameters of Lewis acid component and the choice of Lewis base provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic activity of the resulting FLP catalyst.

引用

页码：5366 / 5372

页数：7

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