Absorption spectrum of the hydrated electron paired with nonreactive metal cations

被引：35

作者：

Bonin, J ^{[1
]}

Lampre, I ^{[1
]}

Mostafavi, M ^{[1
]}

机构：

[1] Univ Paris 11, Chim Phys Lab, ELYSE, UMR CNRS UPS 8000, F-91405 Orsay, France

来源：

RADIATION PHYSICS AND CHEMISTRY | 2005年 / 74卷 / 05期

关键词：

hydrated electron; absorption spectroscopy; alkaline; earth alkaline; terbium;

D O I：

10.1016/j.radphyschem.2005.03.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We studied the effects of eight chloride and five perchlorate salts of monovalent, divalent or trivalent metal cations at high concentration in water on the optical absorption spectrum of the hydrated electron. Whatever the salt, the maximum of the hydrated electron absorption spectrum shifts toward shorter wavelength ("blue shift") as the salt concentration is increased. The effects of the salt concentration, cation charge and counterion on the blue shift are discussed. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：288 / 296

页数：9

共 48 条

[1] ULTRAFAST TRANSIENT-ABSORPTION SPECTROSCOPY OF THE AQUEOUS SOLVATED ELECTRON [J].

ALFANO, JC ;

WALHOUT, PK ;

KIMURA, Y ;

BARBARA, PF .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5996-5998

[2] PULSE RADIOLYSIS STUDIES OF AQUEOUS SODIUM CHLORIDE SOLUTIONS [J].

ANBAR, M ;

THOMAS, JK .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (12) :3829-&

[3] EFFECT OF SOLVENT AND OF SOLUTES ON ABSORPTION SPECTRUM OF SOLVATED ELECTRONS [J].

ANBAR, M ;

HART, EJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (04) :1244-&

[4] Is there any effect of solution microstructure on the solvated electron absorption spectrum in LiCl/H2O solutions? [J].

Asaad, AN ;

Chandrasekhar, N ;

Nashed, AW ;

Krebs, P .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (32) :6339-6343

[5] Dynamics of excited solvated electrons in aqueous solution monitored with femtosecond-time and polarization resolution [J].

Assel, M ;

Laenen, R ;

Laubereau, A .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (13) :2256-2262

[6] PULSE RADIOLYSIS OF AQUEOUS SOLUTIONS OF SOME INORGANIC COMPOUNDS [J].

BAXENDAL.JH ;

FIELDEN, EM ;

KEENE, JP .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1965, 286 (1406) :320-&

[7] PULSE-RADIOLYSIS STUDIES .22. SPECTRUM AND KINETICS OF SODIUM CATION-ELECTRON PAIR IN TETRAHYDROFURAN SOLUTIONS [J].

BOCKRATH, B ;

DORFMAN, LM .

JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (08) :1002-1006

[8] First observation of electron paired with divalent and trivalent nonreactive metal cations in water [J].

Bonin, J ;

Lampre, I ;

Soroushian, B ;

Mostafavi, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (33) :6817-6819

[9] Subpicosecond pump-probe absorption of the hydrated electron: Nonlinear response theory and computer simulation [J].

Bratos, S ;

Leicknam, JC ;

Borgis, D ;

Staib, A .

PHYSICAL REVIEW E, 1997, 55 (06) :7217-7227

[10] Ultrafast transient absorption spectroscopy of the hydrated electron: A theory [J].

Bratos, S ;

Leicknam, JC .

CHEMICAL PHYSICS LETTERS, 1996, 261 (1-2) :117-122

← 1 2 3 4 5 →