Synthesis, Crystal Structure, and Luminescence Property of a New Zinc(II) Complex With Schiff-Base Containing Triazole Propane Ancillary Ligand

被引：11

作者：

Feng, Xun ^{[1
]}

Zhou, Li Li ^{[2
]}

Shi, Zhi-Qiang ^{[1
]}

Shang, Jing-Jing ^{[1
]}

Wu, Xu Hong ^{[1
]}

Wang, Li-Ya ^{[1
,3
]}

Zhou, Jian Guo ^{[3
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[2] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang, Peoples R China

[3] Nanyang Normal Univ, Coll Chem & Pharm Engn, Nanyang, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 09期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

crystal structure; luminescent property; Schiff base; zinc complex;

D O I：

10.1080/15533174.2012.756020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new binuclear zinc complex, namely [Zn(Salpn)(4)(1,3-btp)](n) (1, H(2)salpn = N,N- bis(salicylidene)-1,3-diaminopropane, while 1,3- btp = 1,3-bis (triazole) propane) has been synthesized under one-pot reaction conditions in high yield, and has been characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system, space group of C2/c with a = 18.2270(17), b = 10.7435(10), c = 20.2896(19) angstrom, = 92.9780(10)degrees. The two adjacent zinc-Salpn moieties were connected through the flexible 1,3-btp ligand into a binuclear unit. The bulk purity of the materials of 1 was confirmed through the powder X-ray diffraction (PXRD) experiments. Furthermore, the luminescent property of the complex 1 has also been investigated. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.

引用

页码：1093 / 1098

页数：6

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