A New Cd(II) Coordination Polymer Constructed From Dicarboxylate and N-donor Ligand: Synthesis, Crystal Structure, and Luminescence Property

被引:4
作者
Wang, Aidong [1 ,2 ]
Hu, Fengkai [1 ]
Ke, Zhongcheng [1 ]
Fang, Chen [3 ]
Wei, Wei [1 ]
机构
[1] Coll Huangshan, Dept Chem, Huangshan 245041, Peoples R China
[2] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
[3] Ocean Univ China, Coll Chem & Chem Engn, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao, Shandong, Peoples R China
关键词
cadmium (II); coordination polymer; luminescence; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENCE;
D O I
10.1080/15533174.2012.756030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The 3D coordination polymer {[Cd(dpa)(bpe)]center dot 2H(2)O}n (1)[H(2)dpa = 2,4-biphenyl dicarboxylic acid and bpe = 1,2-bis(4-pyridyl)ethane] was prepared by hydrothermal synthesis and characterized by single X-ray diffraction, FTIR spectra and element analysis. The title complex 1 exhibits an unusual three-dimensional framework with (6,6)-connected (3(2).4(2).5(2).6(8).8) (3(4).4(4).5(4).6(3)) topology. Furthermore, the solid-state photoluminescence property of 1 is investigated at room temperature.
引用
收藏
页码:1146 / 1149
页数:4
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