Regioselective Re(I)-catalyzed coupling of terminal alkynes, Et2NH, and CO2 leading to anti-Markovnikov adducts

被引：12
|
作者：
Jiang, JL [1 ]
Hua, RM [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Innovat Catalysis Program, Key Lab Organ Optoelect & Mol Engn,Minist Educ, Beijing 100084, Peoples R China
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 06期
基金：
中国国家自然科学基金;
关键词：
rhenium addition; terminal alkyne; amine; carbarnate;
D O I：
10.1016/j.tetlet.2005.11.137
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
ReBr(CO)(5)-catalyzed addition of Et2NH and CO2 to terminal alkynes afforded anti-Markovnikov adducts of alkenyl carbamates in good to excellent yield and high regioselectivity. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：953 / 955
页数：3
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