A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol

被引：152

作者：

Anderez-Fernandez, Maria ^{[1
]}

Vogt, Lydia K. ^{[1
]}

Fischer, Steffen ^{[2
]}

Zhou, Wei ^{[1
]}

Jiao, Haijun ^{[1
]}

Garbe, Marcel ^{[1
]}

Elangovan, Saravanakumar ^{[1
]}

Junge, Kathrin ^{[1
]}

Junge, Henrik ^{[1
]}

Ludwig, Ralf ^{[2
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

[2] Univ Rostock, Inst Chem, Dr Lorenz Weg 1, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 02期

基金：

欧盟地平线“2020”;

关键词：

dehydrogenation; homogeneous catalysis; ligand design; manganese; methanol; HYDROGEN-PRODUCTION; IRIDIUM COMPLEX; MILD CONDITIONS; AMINES; ALCOHOLS; KETONES; WATER; TEMPERATURE; LIGANDS; ECONOMY;

D O I：

10.1002/anie.201610182

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.

引用

页码：559 / 562

页数：4

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