The Ultrasmall Palladium Nanoparticles Catalyzed Telomerization of CO2with 1,3-Butadiene at Room Temperature: Selective Synthesis ofδ-Lactone

被引：10

作者：

Wang, Jixiao ^{[1
]}

Feng, Xiujuan ^{[1
]}

Song, Jiliang ^{[1
,2
]}

Gao, Zhanming ^{[1
]}

Wang, Wan-Hui ^{[1
,2
]}

Bao, Ming ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China

[2] Dalian Univ Technol, Sch Chem Engn, Panjin 124221, Peoples R China

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 30期

基金：

中国国家自然科学基金;

关键词：

1; 3-Butadiene; C1 building blocks; Lactones; Palladium nanoparticles; Telomerization; CARBON-DIOXIDE; BUTADIENE; CO2; ACTIVATION; COMPLEXES; LIGANDS;

D O I：

10.1002/slct.202002203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient method for the selective synthesis of delta-lactone from CO(2)and 1,3-butadiene was developed by using ultrasmall palladium nanoparticles as a catalyst for the first time. Palladium nanoparticles (1.90 +/- 0.39 nm) were generated in situ in the presence of Pd(acac)(2), tetrabutylammonium acetate (TBAAc), and PPh(3)as the precatalyst, stabilizer, and reductant, respectively. Maximum yield (86 % with 96 % selectivity) with satisfactory conversion (89 %) and turnover number (1271) was achieved under mild conditions.

引用

页码：9404 / 9408

页数：5

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