Calibration and field evaluation of polar organic chemical integrative sampler (POCIS) for monitoring pharmaceuticals in hospital wastewater

被引:62
作者
Bailly, Emilie [1 ]
Levi, Yves [1 ]
Karolak, Sara [1 ]
机构
[1] Univ Paris 11, Fac Pharmaceut Sci, AgroParisTech, CNRS,Publ Hlth & Environm Lab,UMR 8079, F-92290 Chatenay Malabry, France
关键词
POCIS; Pharmaceuticals; Hospital wastewaters; Water pollution; Modeling; SOLID-PHASE EXTRACTION; PERSONAL CARE PRODUCTS; RISK-ASSESSMENT; MASS-SPECTROMETRY; SURFACE-WATER; SEWAGE WATER; EFFLUENT; CONTAMINANTS; ENVIRONMENT; 5-FLUOROURACIL;
D O I
10.1016/j.envpol.2012.10.025
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The Polar Organic Chemical Integrative Sampler (POCIS) is a new tool for the sampling of organic pollutants in water. We tested this device for the monitoring of pharmaceuticals in hospital wastewater. After calibration, a field application was carried out in a French hospital for six pharmaceutical compounds (Atenolol, Prednisolone, Methylprednisolone, Sulfamethoxazole, Ofloxacin, Ketoprofen). POCIS were calibrated in tap water and wastewater in laboratory conditions close to relevant environmental conditions (temperature, flow velocity). Sampling rates (R-s) were determined and we observed a significant increase with flow velocity and temperature. Whatever the compound, the Rs value was lower in wastewater and the linear phase of uptake was shorter. POCIS were deployed in a hospital sewage pipe during four days and the estimated water concentrations were close to those obtained with twenty-four hour composite samples. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:100 / 105
页数:6
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