Synthesis of Dithiaza- and Dioxadithiazacycloalkanes by Cyclothiomethylation of Arylamines with Formaldehyde and α,ω-Dithiols

被引：4

作者：

Khabibullina, Guzel R. ^{[1
]}

Fedotova, Ekaterina S. ^{[1
]}

Meshcheryakova, Ekaterina S. ^{[1
]}

Buslaeva, Tatyana M. ^{[2
]}

Akhmetova, Vnira R. ^{[1
]}

Ibragimov, Askhat G. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Oktyabrya Ave, Ufa 450075, Russia

[2] Moscow Technol Univ, MV Lomonosov Inst Fine Chem Technol, 78 Vernadskogo Ave, Moscow 119454, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2016年 / 52卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

arylamines; 1,5,3-dithiazepanes; catalysis; cyclothiomethylation; macroheterocycles; multicomponent reaction; sorption of silver(I) and palladium(II); FUNGICIDAL ACTIVITY; HYDROGEN-SULFIDE; MULTICOMPONENT REACTIONS; SORPTION PROPERTIES; PALLADIUM(II); COMPLEXES; AMINES; CH2O; H2S; HETEROCYCLES;

D O I：

10.1007/s10593-016-1975-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New derivatives of 1,5,3-dithiazepanes and macroheterocycles were synthesized by a three-component cyclothiomethylation of arylamines with formaldehyde and alpha,omega-dithiols. The sorption properties of 3-phenyl-1,5,3-dithiazepane and 6-phenyl-1,11-dioxa-4,8-dithia-6-azacyclotridecane applicable for the extraction of Ag(I) and Pd(II) ions from nitric acid solutions at room temperature were studied by a static method.

引用

页码：840 / 848

页数：9

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