Synthesis of Porous Glass Beads and Core-Shell Beads for the Separation of Chiral Anesthetic Gases

被引：5

作者：

Muenzner, Maximilian ^{[1
]}

Dornberg, Gregor ^{[1
]}

Kuester, Christian ^{[1
]}

Enke, Dirk ^{[1
]}

机构：

[1] Univ Leipzig, Inst Tech Chem, Linnestr 3, D-04103 Leipzig, Germany

来源：

CHEMIE INGENIEUR TECHNIK | 2016年 / 88卷 / 11期

关键词：

Anesthetic gases; Core-shell beads; Fluidized-bed reactor; Ionotropic gelation; Porous glass beads; INDUCED PHASE-SEPARATION; ION-EXCHANGE; ISOFLURANE; ENANTIOMERS; SAMPLES;

D O I：

10.1002/cite.201600053

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

For the separation of chiral anesthetic gases suitable support materials for the selectors are necessary. Due to the controlled texture properties porous glass shows a high potential for such applications. In this study porous glass beads with particle diameters of 40 - 400 mu m and 2 - 4mm could be obtained via a special fluidized-bed reactor and the method of ionotropic gelation. Furthermore, the first core-shell beads on the basis of porous glasses could be synthesized via the combination of an ion-exchange induced phase separation and a selective leaching step. The new materials are characterized by a defined mesoporous shell and a non-porous glass core.

引用

页码：1761 / 1769

页数：9

共 25 条

[1]

Aboul-Enein HY, 2000, BIOMED CHROMATOGR, V14, P213, DOI 10.1002/1099-0801(200006)14:4<213::AID-BMC975>3.0.CO

[2]

2-R

[3] Highly porous and monodisperse magnetic silica beads prepared by a green templating method [J].

Abramson, Sebastien ;

Meiller, Clementine ;

Beaunier, Patricia ;

Dupuis, Vincent ;

Perrigaud, Laurent ;

Bee, Agnes ;

Cabuil, Valerie .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (23) :4916-4924

[4] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[5] Stereoselective loss of righting reflex in rats by isoflurane [J].

Dickinson, R ;

White, I ;

Lieb, WR ;

Franks, NP .

ANESTHESIOLOGY, 2000, 93 (03) :837-843

[6] Minimum alveolar anesthetic concentration values for the enantiomers of isoflurane differ minimally [J].

Eger, EI ;

Koblin, DD ;

Laster, MJ ;

Schurig, V ;

Juza, M ;

Ionescu, P ;

Gong, D .

ANESTHESIA AND ANALGESIA, 1997, 85 (01) :188-192

[7] BIOLOGICAL INTERACTIONS BETWEEN POLYSACCHARIDES AND DIVALENT CATIONS - EGG-BOX MODEL [J].

GRANT, GT ;

MORRIS, ER ;

REES, DA ;

SMITH, PJC ;

THOM, D .

FEBS LETTERS, 1973, 32 (01) :195-198

[8]

Haeberle HA, 2004, EUR J ANAESTH, V21, P144

[9] Li+ for Na+ ion-exchange-induced phase separation in borosilicate glass [J].

Hattori, Yuki ;

Wakasugi, Takashi ;

Shiomi, Haruhisa ;

Nishii, Junji ;

Kadono, Kohei .

JOURNAL OF MATERIALS RESEARCH, 2012, 27 (07) :999-1005

[10] Ion-exchange-induced Phase Separation at Dot-like Domains on Glass Surface through a Staining Method [J].

Hattori, Yuki ;

Shiomi, Haruhisa ;

Wakasugi, Takashi ;

Suetsugu, Tatsuya ;

Kadono, Kohei .

CHEMISTRY LETTERS, 2012, 41 (04) :455-457

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