Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates

被引：5

作者：

Alba Millan, Irene R. Marquez ^{[1
]}

Campana, Araceli G. ^{[1
]}

Cuerva, Juan M. ^{[1
]}

机构：

[1] Univ Granada, Dept Organ Chem, E-18071 Granada, Spain

来源：

ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 04期

关键词：

FREE-RADICAL CHEMISTRY; STRAIGHTFORWARD SYNTHESIS; ORGANIC-SYNTHESIS; CASCADE CYCLIZATION; ELECTRON-TRANSFER; TERPENOIDS; TITANOCENE(III); REGIOSELECTIVITY; EPOXYPOLYPRENES; CATALYSIS;

D O I：

10.1039/c4qo00012a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A useful method for the diastereoselective synthesis of vinyl substituted carbo- and heterocycles is described. Highly functionalized structures difficult to achieve by other methodologies are obtained in a single step by this procedure.

引用

页码：373 / 381

页数：9