Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates

被引：5
|
作者：
Alba Millan, Irene R. Marquez [1 ]
Campana, Araceli G. [1 ]
Cuerva, Juan M. [1 ]
机构：
[1] Univ Granada, Dept Organ Chem, E-18071 Granada, Spain
来源：
ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 04期
关键词：
FREE-RADICAL CHEMISTRY; STRAIGHTFORWARD SYNTHESIS; ORGANIC-SYNTHESIS; CASCADE CYCLIZATION; ELECTRON-TRANSFER; TERPENOIDS; TITANOCENE(III); REGIOSELECTIVITY; EPOXYPOLYPRENES; CATALYSIS;
D O I：
10.1039/c4qo00012a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A useful method for the diastereoselective synthesis of vinyl substituted carbo- and heterocycles is described. Highly functionalized structures difficult to achieve by other methodologies are obtained in a single step by this procedure.
引用
收藏
页码：373 / 381
页数：9
相关论文
共 50 条
  • [1] Similarities and differences of epoxide, aldehyde and peroxide initiators for Cp2TiCl-catalyzed styrene living radical polymerizations
    Asandei, Alexandru D.
    Chen, Yanhui
    Moran, Isaac W.
    Saha, Gobinda
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (15) : 3174 - 3182
  • [2] Cp2TiCl-catalyzed epoxide radical ring opening:: A new initiating methodology for graft copolymer synthesis
    Asandei, Alexandru D.
    Saha, Gobinda
    MACROMOLECULES, 2006, 39 (26) : 8999 - 9009
  • [3] Comparing epoxide, aldehyde, halide and peroxide initiators for the Cp2TiCl-catalyzed styrene living radical polymerization
    Asandei, Alexandru D.
    Chen, Yanhui
    Saha, Gobinda
    Moran, Isaac W.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [4] Effect of additives in the Cp2TiCl-catalyzed living radical polymerization of styrene initiated by epoxide radical ring opening
    Asandei, Alexandru D.
    Moran, Isaac W.
    Saha, Gobinda
    Chen, Yanhui
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [5] Toward Cp2TiCl-catalyzed living radical polymerization of isoprene
    Asandei, AD
    Saha, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U4250 - U4250
  • [6] Solvent effect in the Cp2TiCl-catalyzed living radical polymerization of styrene initiated by epoxide radical ring opening
    Asandei, Alexandru D.
    Moran, Isaac W.
    Chen, Yanhui
    Saha, Gobinda
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [7] Effect of temperature and stoichiometry in the Cp2TiCl-catalyzed living radical polymerization of styrene initiated by epoxide radical ring opening
    Asandei, Alexandru D.
    Moran, Isaac W.
    Saha, Gobinda
    Chen, Yanhui
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [8] Carbonyl initiated Cp2TiCl-catalyzed controlled radical polymerization of isoprene
    Asandei, Alexandru D.
    Olumide, Adebolu
    Yu, Hyun Seok
    Simpson, Christopher P.
    Gilbert, Megan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [9] Peroxide initiated, Cp2TiCl-catalyzed living radical polymerization of styrene
    Asandei, Alexandru D.
    Saha, Gobinda
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [10] Effect of reducing agents in the Cp2TiCl-catalyzed living radical polymerization of styrene initiated by epoxide radical ring opening
    Asandei, Alexandru D.
    Moran, Isaac W.
    Saha, Gobinda
    Chen, Yanhui
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
12345