Broadly tunable emission from Ca2Al2SiO7: Bi phosphors based on crystal field modulation around Bi ions

被引：17

作者：

Li, Minhong ^{[1
]}

Wang, Lili ^{[1
]}

Ran, Weiguang ^{[1
]}

Liu, Qingzhi ^{[1
]}

Ren, Chunyan ^{[1
]}

Jiang, Haiyan ^{[1
]}

Shi, Jinsheng ^{[1
]}

机构：

[1] Qingdao Agr Univ, Dept Chem & Pharmaceut, Qingdao 266109, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 11期

关键词：

ENERGY-TRANSFER; LUMINESCENCE; TB3+; SITE; MN2+; EU2+; EU3+;

D O I：

10.1039/c6nj01755j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New non-rare-earth activated phosphors were discovered and have attracted much attention in the field of energy-efficient LED lighting. For instance Bi3+, when mixed into different matrix materials, can realize multiple luminescence intensities ranging from 400 to 700 nm. The tunable emission results from the susceptibility of bismuth naked 6s electrons to the crystal field surrounding Bi3+. In this work, we report the broadly adjustable emission of Bi3+ doped Ca2Al2SiO7 phosphors by modifying the local environment around Bi3+. When M+ ( M = Li, Na and K) is incorporated into the Ca2Al2SiO7 lattice, the luminescence intensity is improved greatly. In addition, the position of the emission peak of Bi3+ shifts from 382 to 416 nm upon varying the relative ratio of B3+/Al3+/Ga3+ ions. The spectral red-shift behaviour is attributed to the enhancement of crystal field strength surrounding Bi3+. These results are promising for investigation of the luminescence properties of Bi3+.

引用

页码：9579 / 9585

页数：7

共 27 条

[1] ENERGY TRANSFER IN OXIDIC PHOSPHORS [J].

BLASSE, G .

PHYSICS LETTERS A, 1968, A 28 (06) :444-&

[2] Luminescence Properties and Energy Transfer of Eu/Mn-Coactivated Mg2Al4Si5O18 as a Potential Phosphor for White-Light LEDs [J].

Chen, Jian ;

Liu, Yangai ;

Fang, Minghao ;

Huang, Zhaohui .

INORGANIC CHEMISTRY, 2014, 53 (21) :11396-11403

[3] A green-yellow emitting oxyfluoride solid solution phosphor Sr2Ba(AlO4F)1-x(SiO5)x:Ce3+ for thermally stable, high color rendition solid state white lighting [J].

Denault, Kristin A. ;

George, Nathan C. ;

Paden, Sara R. ;

Brinkley, Stuart ;

Mikhailovsky, Alexander A. ;

Neuefeind, Joerg ;

DenBaars, Steven P. ;

Seshadri, Ram .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (35) :18204-18213

[4] New yellowish-green light emitting thin film: 89Al2O3•5CeCl3•3EuCl3•3TbCl3 [J].

Gonzalez, W. ;

Alvarez, E. ;

Righini, G. C. ;

Caldino, U. .

OPTICAL MATERIALS, 2013, 35 (06) :1304-1308

[5] Near UV-pumped yellow-emitting Eu2+-doped Na3K(Si1-xAlx)8O16±δ phosphor for white-emitting LEDs [J].

Han, Ji Yeon ;

Im, Won Bin ;

Lee, Ga-yeon ;

Jeon, Duk Young .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) :8793-8798

[6] A Novel Single-Composition Trichromatic White-Light Ca3Y(GaO)3(BO3)4:Ce3+,Mn2+,Tb3+ Phosphor for UV-Light Emitting Diodes [J].

Huang, Chien-Hao ;

Chen, Teng-Ming .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (05) :2349-2355

[7] Structure and photoluminescence properties of novel Ca2NaSiO4F:Re (Re = Eu2+, Ce3+, Tb3+) phosphors with energy transfer for white emitting LEDs [J].

Jiao, Mengmeng ;

Jia, Yongchao ;

Lu, Wei ;

Lv, Wenzhen ;

Zhao, Qi ;

Shao, Baiqi ;

You, Hongpeng .

JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (21) :4304-4311

[8] Tunable Blue-Green-Emitting Ba3LaNa(PO4)3F:Eu2+,Tb3+ Phosphor with Energy Transfer for Near-UV White LEDs [J].

Jiao, Mengmeng ;

Guo, Ning ;

Lu, Wei ;

Jia, Yongchao ;

Lv, Wenzhen ;

Zhao, Qi ;

Shao, Baiqi ;

You, Hongpeng .

INORGANIC CHEMISTRY, 2013, 52 (18) :10340-10346

[9] Broadly tuning Bi3+ emission via crystal field modulation in solid solution compounds (Y,Lu,Sc) VO4:Bi for ultraviolet converted white LEDs [J].

Kang, Fengwen ;

Peng, Mingying ;

Yang, Xiaobao ;

Dong, Guoping ;

Nie, Guochao ;

Liang, Weijiang ;

Xu, Shanhui ;

Qiu, Jianrong .

JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (30) :6068-6076

[10] Broadly Tunable Emission from CaMoO4: Bi Phosphor Based on Locally Modifying the Microenvironment Around Bi3+ Ions [J].

Kang, Fengwen ;

Peng, Mingying ;

Xu, Shanhui ;

Ma, Zhijun ;

Dong, Guoping ;

Qiu, Jianrong .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (08) :1373-1380

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