Synthesis in a gel and sorption properties of N-2-sulfoethyl chitosan

被引:25
作者
Pestov, A. V. [1 ]
Petrova, Yu S. [2 ]
Bukharova, A. V. [2 ]
Neudachina, L. K. [2 ]
Koryakova, O. V. [1 ]
Matochkina, E. G. [1 ]
Kodess, M. I. [1 ]
Yatluk, Yu G. [1 ]
机构
[1] Russian Acad Sci, Postovskii Inst Organ Synth, Ural Div, Ekaterinburg, Russia
[2] Yeltsin Ural Fed Univ, Ekaterinburg, Russia
关键词
DERIVATIVES; MEMBRANES; GLUCAN;
D O I
10.1134/S1070427213020225
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new procedure was developed for preparation of chelate amino-containing polymer N-2-sulfoethyl chitosan by synthesis in a gel through the reaction between chitosan and sodium 2-bromoethanesulfonate, yielding a polymer with the degree of substitution of up to 0.5. The structure of the resulting polymers was confirmed by H-1 NMR spectroscopy. The sorption characteristics with respect to transition and alkaline-earth metal ions were determined for the cross-linked polymers.
引用
收藏
页码:269 / 272
页数:4
相关论文
共 24 条
[1]   Water-soluble N-carboxymethylchitosan derivatives: Preparation, characteristics and its application [J].
An, Nguyen Tien ;
Thien, Do Truong ;
Dong, Nguyen Thi ;
Le Dung, Pham .
CARBOHYDRATE POLYMERS, 2009, 75 (03) :489-497
[2]   Metallation of functional resins with copper acetate:: control of metal speciation and catalytic activity in C-N coupling reactions [J].
Biffis, A ;
Filippi, F ;
Palma, G ;
Lora, S ;
Maccà, C ;
Corain, B .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) :213-220
[3]   PROTECTIVE EFFECT OF SULFOETHYLGLUCAN AGAINST HEXAVALENT CHROMIUM [J].
CHORVATOVICOVA, D ;
KOVACIKOVA, Z ;
SANDULA, J ;
NAVAROVA, J .
MUTATION RESEARCH, 1993, 302 (04) :207-211
[4]   Formation and characterization of chitosan membranes [J].
Clasen, C. ;
Wilhelms, T. ;
Kulicke, W. -M. .
BIOMACROMOLECULES, 2006, 7 (11) :3210-3222
[5]   SYNTHESIS AND ANTITUMOR-ACTIVITY OF SULFOALKYL DERIVATIVES OF CURDLAN AND LICHENAN [J].
DEMLEITNER, S ;
KRAUS, J ;
FRANZ, G .
CARBOHYDRATE RESEARCH, 1992, 226 (02) :247-252
[6]  
Ebringerova A, 1998, J APPL POLYM SCI, V67, P1523
[7]   INVESTIGATION OF THE HYDRODYNAMIC PROPERTIES OF CHITOSAN SOLUTIONS [J].
GAMZAZADE, AI ;
SLIMAK, VM ;
SKLJAR, AM ;
STYKOVA, EV ;
PAVLOVA, SSA ;
ROGOZIN, SV .
ACTA POLYMERICA, 1985, 36 (08) :420-424
[8]   Anion effects on anti-microbial activity of poly[1-vinyl-3-(2-sulfoethyl imidazolium betaine)] [J].
Garg, Godawari ;
Chauhan, Ghanshyam S. ;
Gupta, Reena ;
Ahn, J-H. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 344 (01) :90-96
[9]   Polymer monoliths with low Hydrophobicity for strong cation-exchange capillary liquid chromatography of peptides and proteins [J].
Gu, Binghe ;
Li, Yun ;
Lee, Milton L. .
ANALYTICAL CHEMISTRY, 2007, 79 (15) :5848-5855
[10]   Stationary and mobile phases in hydrophilic interaction chromatography: a review [J].
Jandera, Pavel .
ANALYTICA CHIMICA ACTA, 2011, 692 (1-2) :1-25