Self-Assembly of Poly(γ-benzyl L-glutamate)-block-poly(ethylene glycol) and Poly(γ-benzyl L-glutamate)-graft-poly(ethylene glycol) Blend in Ethanol

被引：0
作者：
Zhu, Guo-Quan [1 ]
Wang, Fa-Gang [1 ]
Li, Guo-Chang [1 ]
Gao, Qiao-Chun [1 ]
Liu, Yu-Ying [1 ]
机构：
[1] Shandong Univ Technol, Sch Mat Sci & Engn, Zibo 255049, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 06期
关键词：
Polypeptide copolymer blend; Self-assembly; Critical micelle concentration; Morphology; POLY(ETHYLENE OXIDE); POLYMERIC MICELLES; GRAFT COPOLYMER; L-GLUTAMATE); MICELLIZATION; MIXTURES;
D O I：
10.14233/ajchem.2013.13517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Poly(gamma-benzyl L-glutamate)-block-poly(ethylene glycol) (PBLG-block-PEG) and poly(gamma-benzyl L-glutamate)-graft-poly(ethylene glycol) (PBLG-graft-PEG) were synthesized by a standard N-carboxyl-gamma-benzyl-L-glutamate anhydride method and by an ester exchange reaction, respectively. The self-association behaviours of PBLG-block-PEG/PBLG-graft-PEG blend in ethanol were investigated by transmission electron-microscopy viscometry. It was showed that the polypeptide copolymer blend could self-assemble to form polymeric micelles with a core-shell structure in the shape of tree-like. Effects of the testing temperature and the weight ratio of PBLG-block-PEG to PBLG-graft-PEG on the critical micelle concentration of polypeptide copolymer blend in ethanol were studied.
引用
收藏
页码：3060 / 3062
页数：3
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