Investigation of Cu, Pb, Zn, As, Sb distribution during the lead semiproducts and copper-zinc concentrate comelting

被引:5
作者
Dosmukhamedov, N. K. [1 ]
Fedorov, A. N. [2 ]
Zholdasbay, E. E. [1 ]
Argyn, A. A. [1 ]
机构
[1] Satbaev Univ, Dept Met & Mineral Proc, Alma Ata, Kazakhstan
[2] Natl Univ Sci & Technol MISiS, Dept Nonferrous Met & Gold, Moscow, Russia
来源
NON-FERROUS METALS | 2020年 / 01期
关键词
lead semiproducts; copper-zinc concentrate; charge; distribution; non-ferrous metals; impurities; comelting; direct smelting;
D O I
10.17580/nfm.2020.01.02
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The issues of smelting of difficult for treatment high-sulfur copper-zinc concentrate together with semiproducts and reverts of lead manufacture are considered. The possibility of direct extraction of copper, lead and zinc from copper-zinc concentrate to target products in a one-stage process is substantiated. Presented are the results of laboratory mettings for coprocessing of lead semiproducts, reverts and copper-zinc concentrate at a temperature of 1250 C under the melt bubbling conditions. High indexes of metal extraction into target products were achieved: copper into matte - up to 95% against 88.9% according to the existing technology; lead into lead bullion - up to 94% against 70.8% and zinc into slag - up to 95% compared to 83.7%. Extraction of arsenic and antimony into dust - 91 and 92.3% compared to 69.5% and 59.8%, respectively, which provides circumstances for their removal from the overall process chain of lead production. The use of the proposed solution in lead production will lessen the load on the environment; improve the process figures of the blast concentrating smelting process by reducing the loss of copper, lead with slag and high recovery of arsenic and antimony into dust. Compared to the existing technology, the consumption of coke and quartz flux is significantly reduced: from 6.7 to 2.5% and from 12.5 to 4.7% of the charge weight, respectively. The results of comelting of lead semiproducts and copper-zinc concentrate can form the basis for the development of a new manufacturing method.
引用
收藏
页码:8 / 14
页数:7
相关论文
共 18 条
[1]  
[Булатов К.В. Bulatov K.V.], 2014, [Цветные металлы, Tsvetnye metally], P39
[2]   Thermodynamic Modeling of Arsenic in Copper Smelting Processes [J].
Chen, Chunlin ;
Zhang, Ling ;
Jahanshahi, Sharif .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2010, 41 (06) :1175-1185
[3]  
Chen L, 2013, 4TH INTERNATIONAL SYMPOSIUM ON HIGH-TEMPERATURE METALLURGICAL PROCESSING, P49
[4]  
Dosmukhamedov N. K., 2020, KOMPLEKSNOE ISPOLZOV, V1, P31, DOI DOI 10.31643/2020/6445.04
[5]  
Dosmukhamedov N. K., 2016, TSVETNYE METALLY, P45, DOI [10.17580/ tsm.2016.08.06, DOI 10.17580/TSM.2016.08.06]
[6]   Metal Recovery from Converter Slags Using a Sulfiding Agent [J].
Dosmukhamedov, Nurlan ;
Egizekov, Maksut ;
Zholdasbay, Erzhan ;
Kaplan, Valery .
JOM, 2018, 70 (10) :2400-2406
[7]   Efficient Removal of Arsenic and Antimony During Blast Furnace Smelting of Lead-Containing Materials [J].
Dosmukhamedov, Nurlan ;
Kaplan, Valery .
JOM, 2017, 69 (02) :381-387
[8]  
Han J., 2015, METALL MATER TRANS B, V47, P344
[9]   High temperature phase relations in FeOX(X=1 and 1.33)-CaO-SiO2 systems under various oxygen partial pressure [J].
Henao, HM ;
Kongoli, F ;
Itagaki, K .
MATERIALS TRANSACTIONS, 2005, 46 (04) :812-819
[10]   Phase Equilibria Study of the ZnO-"FeO"-SiO2-Al2O3 System at Po2 10-8 atm [J].
Liu, Hongquan ;
Cui, Zhixiang ;
Chen, Mao ;
Zhao, Baojun .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2016, 47 (02) :1113-1123