Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

被引：116
作者：
González-Arellano, C
Corma, A
Iglesias, M
Sánchez, F
机构：
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
[3] CSIC, Inst Ciencia Mat, Madrid 28049, Spain
来源：
JOURNAL OF CATALYSIS | 2006年 / 238卷 / 02期
关键词：
gold catalysts for carbon-carbon bond formation; gold(I) catalysts for Suzuki cross-coupling; gold(III) catalysts for homocoupling C-C formation;
D O I：
10.1016/j.jcat.2005.12.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Trinuclear triphenylphosphine 1,2Au(I) complexes with the [N,N,0,]-tridentate unsymmetrical Schiff bases (1,2) catalyze the Suzuki cross-coupling reaction to afford nonsymmetrical biaryls in good yields, whereas the 1,2Au(111) complexes give only arylboronic homocoupling (c) 2005 Elsevier Inc. All rights reserved.
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收藏
页码：497 / 501
页数：5
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