Some cutting oil formulations based on local prepared emulsifiers part I: Preparation of some emulsifiers based on local raw materials to stabilize cutting oil emulsions

被引:4
作者
Al Sabagh, AM [1 ]
Maysour, NA
Nasser, NM
Sorour, MR
机构
[1] Egyptian Petr Res Inst, Cairo, Egypt
[2] CoPetrol Co, Alexandria, Egypt
关键词
cutting fluids; emulsifiers; soluble oils; emulsion stability; coupling agents; cutting oil emulsions;
D O I
10.1080/01932690500267215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The first main target of this work is to synthesis some emulsifiers from local raw materials used for cutting oil formulations. Seventeen emulsifiers (15 nonionic and 2 anionic) were prepared from locally available materials such as linear alkyl benzene sulfonic acid (LABSA), glycerol, polyethylene glycol, and maleic anhydride. Their chemical structures were confirmed using FTIR. The surface tension for the emulsifiers was measured at 25 degrees C, and the surface and thermodynamic properties were calculated based on the surface tension parameters. The formulations of cutting oil fluids were prepared using these emulsifiers. The second target is to investigate the stability of soluble oil blends and emulsion stability of soluble oil in water. The results are discussed in the light of surface-active properties and chemical structure of emulsifiers.
引用
收藏
页码:239 / 250
页数:12
相关论文
共 19 条
  • [11] Analysis of ethoxylated fatty amines. Comparison of methods for the determination of molecular weight
    Lang, RF
    Parra-Diaz, D
    Jacobs, D
    [J]. JOURNAL OF SURFACTANTS AND DETERGENTS, 1999, 2 (04) : 503 - 513
  • [12] Men GF, 2001, PETROL SCI TECHNOL, V19, P1251
  • [13] OCONNOR JJ, 1968, STANDARD HDB LUBRICA, P23
  • [14] PANDAZARAS CN, 2001, TRIBO TEST, V7, P229
  • [15] RENAL J, 1972, Patent No. 1268557
  • [16] Schwartz R. B., 1952, U.S. Patent, Patent No. [2588771, 2,588,771]
  • [17] SHOJI W, 1982, LUB ENG, V38, P412
  • [18] TRENT EM, 1984, METAL CUTTING, P221
  • [19] 1947, Patent No. 2422177