A 2-(2′-hydroxyphenyl)quinazolin-4(3H)-one derived enaminone for fluorescence detection of Pd2+

被引:11
|
作者
Tang, Lijun [1 ]
Ding, Shuangli [1 ]
Yan, Xiaomei [2 ]
机构
[1] Bohai Univ, Dept Chem, Jinzhou 121013, Peoples R China
[2] Dalian Med Univ, Coll Lab Med, Dalian 116044, Peoples R China
基金
中国国家自然科学基金;
关键词
Pd2+ recognition; Quinazolin-4(3H)-one; Enaminone; Cell imaging; LIVING CELLS; HUMAN HEALTH; SCHIFF-BASE; PALLADIUM; PROBE; PLATINUM; SPECTROMETRY; WATER; IONS;
D O I
10.1016/j.inoche.2016.10.041
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A 2-(2'-hydroxyphenyl)quinazolin-4(3H)-one derived enaminone (QA) has been developed as a fluorescent probe. In PBS buffered (10 mM, pH = 7.4) water solution, QA displays high selectivity to Pd2+ over other metal ions with a complete fluorescence quenching at 538 nm. Probe QA interacts with Pd2+ through a 1:1 binding stoichiometry with a detection limit of 4.85 x 10(-7) M. Potential applications of QA for Pd2+ detection in real water samples and living cell imaging were also investigated. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:35 / 38
页数:4
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