Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application

被引：33
作者：
Haraguchi, Naoki
Kiyono, Hitomi
Takemura, Yu
Itsuno, Shinichi
机构：
[1] Toyohashi, 441-8580, 1-1 Hibarigaoka, Tenpaku-Cho
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 33期
关键词：
ORGANIC CATALYSIS; TRANSFER HYDROGENATION; SYNTHETIC ENZYMES; EPOXIDATION; IMMOBILIZATION; STRATEGIES; ALKYLATIONS; ADVENT;
D O I：
10.1039/c2cc18115k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Main-chain polymers of chiral imidazolidinone were successfully synthesized by reaction of chiral imidazolidinone dimers with disulfonic acid. Chiral imidazolidinones were incorporated into the main-chain of the polymer by ionic bonding. These polymers could be used as polymeric chiral organocatalysts for asymmetric Diels-Alder reactions.
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收藏
页码：4011 / 4013
页数：3
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