A novel system comprising metalloporphyrins and cyclohexene for the biomimetic aerobic oxidation of toluene

被引：22

作者：

Chen, Hong-Yu ^{[1
]}

Lv, Meng ^{[1
]}

Zhou, Xian-Tai ^{[2
]}

Wang, Jie-Xiang ^{[1
]}

Han, Qi ^{[2
]}

Ji, Hong-Bing ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem, Fine Chem Ind Res Inst, Guangzhou 510275, Guangdong, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem Engn & Technol, Fine Chem Ind Res Inst, Zhuhai 519082, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2018年 / 109卷

基金：

中国国家自然科学基金;

关键词：

Metalloporphyrins; Hydrogen donor; Oxidation; Toluene; In situ EPR; MOLECULAR-OXYGEN; IRON; AIR;

D O I：

10.1016/j.catcom.2018.02.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, a novel system comprising metalloporphyrins and cyclohexene for the biomimetic aerobic oxidation of toluene and its derivatives was developed, which exhibited relatively benign reaction conditions, good catalytic activity, and broad substrate scope. Based on a series of in situ EPR (Electron Paramagnetic Resonance) and UV-vis experiments, the effect of cyclohexene on the reaction and the catalytic mechanism were preliminarily investigated.

引用

页码：76 / 79

页数：4

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