Catalytic hydrogenation and deuteration of phospholipid model membranes with a water-soluble chlorotris(1,3,5-triaza-7-phosphaadamantane)rhodium(I) complex catalyst

被引：20
|
作者：
Nádasdi, L
Joó, F
机构：
[1] Lajos Kossuth Univ, Hungarian Acad Sci, Res Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary
[2] Lajos Kossuth Univ, Inst Phys Chem, H-4010 Debrecen, Hungary
来源：
INORGANICA CHIMICA ACTA | 1999年 / 293卷 / 02期
基金：
匈牙利科学研究基金会;
关键词：
catalytic hydrogenation; phospholipids; rhodium complexes; phosphaadamantane complexes;
D O I：
10.1016/S0020-1693(99)00268-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The water-soluble chlorotris(1,3,5-triaza-7-phosphaadamantane)rhodium(I) [RhCl(PTA)(3)], was successfully employed for hydrogenation of phospholipid liposomes as model membranes in aqueous media under mild conditions. The highest conversion was achieved at pH 4.70. Formation of asymmetrically dideuterated lipids, together with isomerization and kinetic results revealed the important role of reversible formation of an alkyl-rhodium intermediate in the mechanism. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：218 / 222
页数：5
相关论文
共 7 条
  • [1] Synthesis of water-soluble ruthenium clusters by reaction with PTA (1,3,5-triaza-7-phosphaadamantane)
    Mager, Nathalie
    Robeyns, Koen
    Hermans, Sophie
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 794 : 48 - 58
  • [2] Unusual Water-Soluble Imino Phosphine Ligand: Enamine and Imine Derivatives of 1,3,5-Triaza-7-phosphaadamantane (PTA)
    Enow, Raphel A. E.
    Lee, Wei-Chih
    Cournoyer, Travis D.
    Sunderland, Travis L.
    Frost, Brian J.
    INORGANIC CHEMISTRY, 2018, 57 (15) : 9142 - 9152
  • [3] Water-soluble Ru(II)- and Ru(III)-halide-PTA complexes (PTA=1,3,5-triaza-7-phosphaadamantane): Chemical and biological properties
    Battistin, F.
    Scaletti, F.
    Balducci, G.
    Pillozzi, S.
    Arcangeli, A.
    Messori, L.
    Alessio, E.
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2016, 160 : 180 - 188
  • [4] Neutral 1,3,5-Triaza-7-phosphaadamantane-Ruthenium(II) Complexes as Precursors for the Preparation of Highly Water-Soluble Derivatives
    Battistin, Federica
    Balducci, Gabriele
    Iengo, Elisabetta
    Demitri, Nicola
    Alessio, Enzo
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (17) : 2850 - 2860
  • [5] Water-Soluble Ruthenium(II) Carbonyls with 1,3,5-Triaza-7-phosphoadamantane
    Battistin, Federica
    Balducci, Gabriele
    Milani, Barbara
    Alessio, Enzo
    INORGANIC CHEMISTRY, 2018, 57 (12) : 6991 - 7005
  • [6] Visible-Light Photoisomerization and Photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)4Cl2] in Organic Solvent and Water
    Girotti, Rugiada
    Romerosa, Antonio
    Manas, Sonia
    Serrano-Ruiz, Manuel
    Perutz, Robin N.
    INORGANIC CHEMISTRY, 2009, 48 (08) : 3692 - 3698
  • [7] Transformations of the Vaska-type complex trans-[RhCl(CO)(PTA)2] (PTA=1,3,5-triaza-7-phosphaadamantane) during stepwise addition of HCl: Synthesis, characterization and crystal structure of trans-[RhCl2(PTA)(PTAH)]
    Smolenski, Piotr
    Kirillov, Alexander M.
    da Silva, M. Fatima C. Guedes
    Pombeiro, Armando J. L.
    INORGANICA CHIMICA ACTA, 2011, 378 (01) : 342 - 346
1