Synthesis of indole-based propellane derivatives via Weiss-Cook condensation, Fischer indole cyclization, and ring-closing metathesis as key steps

被引：17

作者：

Kotha, Sambasivarao ^{[1
]}

Chinnam, Ajay Kumar ^{[1
]}

Tiwari, Arti ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Powai, India

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷

关键词：

allylation; indole derivatives; propellanes; ring-closing metathesis; Weiss-Cook condensation; IMINIUM ION CYCLIZATION; CONCISE TOTAL-SYNTHESIS; GENERAL-APPROACH; A-C; ALKALOIDS; (+/-)-MINFIENSINE; POLYQUINENES; CONSTRUCTION; MINFIENSINE; SERIES;

D O I：

10.3762/bjoc.9.307

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of highly functionalized indole-based [n.3.3]propellane derivatives is described. The synthesis of the propellane derivatives involves a Weiss-Cook condensation, a Fischer indole cyclization, and a ring-closing metathesis as key steps.

引用

页码：2709 / 2714

页数：6

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