Recent developments in copper nanoparticle-catalyzed synthesis of 1,4-disubstituted 1,2,3-triazoles in water

被引：25

作者：

Lal, Kashmiri ^{[1
]}

Rani, Poonam ^{[1
]}

机构：

[1] Guru Jambheshwar Univ Sci & Technol, Dept Chem, Hisar 125001, Haryana, India

来源：

ARKIVOC | 2016年

关键词：

Click chemistry; copper nanoparticles; 1,4-disubstituted 1,2,3-triazoles; green chemistry; heterogeneous catalysis; AZIDE-ALKYNE CYCLOADDITION; MULTICOMPONENT CLICK SYNTHESIS; SURFACE ORGANOMETALLIC CHEMISTRY; ONE-POT SYNTHESIS; TERMINAL ALKYNES; 1,3-DIPOLAR CYCLOADDITION; RECYCLABLE CATALYST; HETEROGENEOUS CATALYST; IODIDE NANOPARTICLES; REUSABLE CATALYST;

D O I：

10.3998/ark.5550190.p009.593

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Cu(I)-catalyzed 1,3-dipolar cycloaddition between terminal alkynes and organic azides generating 1,4-disubstituted 1,2,3-triazoles has attracted considerable attention owing to its consistency, specificity, and biocompatibility. Copper nanoparticles supported on various supports such as agarose, cellulose, chitosan, charcoal, activated carbon, silica gel, aminoclay, polymer support like poly(styrene-co-maleimide) (SMI) and polyvinylpyrrolidone (PVP) have been utilized as heterogeneous catalyst for the synthesis of 1,2,3-triazoles. This review summarizes various straightforward and efficient methods for the regioselective synthesis of 1,4-disubstituted 1,2,3-triazoles utilizing supported copper nanoparticles as a source of the heterogeneous catalytic species and water as solvent.

引用

页码：307 / 341

页数：35

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