Preparation of a nanowire-structured polyaniline composite and gas sensitivity studies

被引:69
作者
Ma, XF [1 ]
Li, G
Wang, M
Cheng, YN
Bai, R
Chen, HZ
机构
[1] Zhejiang Univ, Dept Polymer Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Biomed Engn, State Key Lab Biosensors, Hangzhou 310027, Peoples R China
[3] Shandogn Res Inst Nonmet Mat, Jinan 250031, Peoples R China
关键词
inducement effect; nanostructures; polyaniline; sensors; surfactants;
D O I
10.1002/chem.200500763
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To obtain organic nanowire sensors with high sensitivity and rapid response times, based on the inducement effect of surfactants during in situ polymerization, nanostructured polyaniline composites are obtained by using a chemical oxidation method by adding a small amount of surfactant. A casting method is employed on interdigitated carbon electrodes. The gas sensitivity and response rates of a film with nanowire structure are much better than those of conventional polyaniline films produced by means of organic solution spin coating methods. The film described in this work shows good selectivity to trimethylamine and other related gases and, the reaction being reversible with the ues of high-purity nitrogen.
引用
收藏
页码:3254 / 3260
页数:7
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