A redox-active luminescent ytterbium based single molecule magnet

被引：176
|
作者：
Pointillart, Fabrice [1 ]
Le Guennic, Boris [1 ]
Golhen, Stephane [1 ]
Cador, Olivier [1 ]
Maury, Olivier [2 ]
Ouahab, Lahcene [1 ]
机构：
[1] Univ Rennes 1, CNRS, Inst Sci Chim Rennes, UMR 6226, F-35042 Rennes, France
[2] Univ Lyon 1, ENS Lyon, CNRS, Lab Chim,UMR 5182, F-69364 Lyon 07, France
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 06期
关键词：
ENERGY-TRANSFER; TETRATHIAFULVALENE; BEHAVIOR; ANISOTROPY; DINUCLEAR;
D O I：
10.1039/c2cc37635k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A redox active dinuclear complex [Yb(tta)(2)(L-1)(L-2)](2)center dot 1.4(CH2Cl2) displays single molecule magnet behaviour with M-J = +/- 7/2 ground state. The anisotropic barrier Delta is evaluated by the three dc data fit, ac analysis and emission spectrum demonstrating the correlation between magnetic and optical properties.
引用
收藏
页码：615 / 617
页数：3
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