Coconut shell-based microporous carbons for CO2 capture

被引:169
作者
Ello, Aime Serge [1 ,2 ]
de Souza, Luiz K. C. [1 ,3 ]
Trokourey, Albert [2 ]
Jaroniec, Mietek [1 ]
机构
[1] Kent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
[2] Univ Felix Houphouet Boigny Cocody, Lab Chim Phys, Abidjan, Cote Ivoire
[3] ICEN Fed Univ Para UFPA, Dept Chem, Lab Catalysis & Oilchem, BR-66075110 Belem, Para, Brazil
关键词
Coconut shell; Activation; CO2; adsorption; Microporous carbons; ACTIVATED CARBON; ADSORPTION; DIOXIDE; ADSORBENTS; MONOLITH; BIOMASS; KOH;
D O I
10.1016/j.micromeso.2013.07.008
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Microporous carbons were prepared from coconut shell by one-step activation with CO2. The specific surface area and micropore volume were tuned from 686 to 1327 m(2)/g and from 0.31 to 0.65 cm(3)/g, respectively, by varying time of CO2 activation. The maximum adsorption of CO2 on these carbons at 760 mmHg reached the values 3.9 and 5.6 mmol/g at 25 and 0 degrees C, respectively, which are comparable to the reported values of CO2 adsorption capacity on vegetable origin carbons. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码:280 / 283
页数:4
相关论文
共 29 条
[1]   CO2 capture using mesoporous alumina prepared by a sol-gel process [J].
Chen, Chao ;
Ahn, Wha-Seung .
CHEMICAL ENGINEERING JOURNAL, 2011, 166 (02) :646-651
[2]   Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources [J].
Choi, Sunho ;
Drese, Jeffrey H. ;
Jones, Christopher W. .
CHEMSUSCHEM, 2009, 2 (09) :796-854
[3]   Pyrolysis and gasification of pellets from sugar cane bagasse and wood [J].
Erlich, Catharina ;
Bjornbom, Emilia ;
Bolado, David ;
Giner, Marian ;
Fransson, Torsten H. .
FUEL, 2006, 85 (10-11) :1535-1540
[4]   Porous structure and adsorptive properties of pineapple peel based activated carbons prepared via microwave assisted KOH and K2CO3 activation [J].
Foo, K. Y. ;
Hameed, B. H. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 148 (01) :191-195
[5]   Development of micro-mesoporous carbons from several seed hulls under varying conditions of activation [J].
Girgis, Badie S. ;
Soliman, Ashraf M. ;
Fathy, Nady A. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 142 (2-3) :518-525
[6]   Hierarchically porous phenolic resin-based carbons obtained by block copolymer-colloidal silica templating and post-synthesis activation with carbon dioxide and water vapor [J].
Gorka, Joanna ;
Jaroniec, Mietek .
CARBON, 2011, 49 (01) :154-160
[7]   Rapid Synthesis of Nitrogen-Doped Porous Carbon Monolith for CO2 Capture [J].
Hao, Guang-Ping ;
Li, Wen-Cui ;
Qian, Dan ;
Lu, An-Hui .
ADVANCED MATERIALS, 2010, 22 (07) :853-+
[8]   Agricultural residues as precursors for activated carbon production - A review [J].
Ioannidou, O. ;
Zabaniotou, A. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2007, 11 (09) :1966-2005
[9]   Physicochemical foundations for characterization of adsorbents by using high-resolution comparative plots [J].
Jaroniec, M ;
Kaneko, K .
LANGMUIR, 1997, 13 (24) :6589-6596
[10]   Can Metal-Organic Framework Materials Play a Useful Role in Large-Scale Carbon Dioxide Separations? [J].
Keskin, Seda ;
van Heest, Timothy M. ;
Sholl, David S. .
CHEMSUSCHEM, 2010, 3 (08) :879-891