A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

被引：30

作者：

Vanhaecht, Stef ^{[1
]}

Jacobs, Jeroen ^{[1
]}

Van Meervelt, Luc ^{[1
]}

Parac-Vogt, Tatjana N. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Leuven, Belgium

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 44期

关键词：

ELECTRON-TRANSFER REACTIONS; HYBRID; CLUSTERS; NANOSTRUCTURES; ASSEMBLIES; HETEROPOLYMOLYBDATES; DAWSON;

D O I：

10.1039/c5dt03559g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new azide functionalized Anderson polyoxometalate was synthesized, fully characterized and subsequently used as a building block for further POM post-functionalization with organic compounds through a copper catalyzed azide-alkyne cycloaddition (CuAAC) reaction. Optimization of the reaction conditions led to an efficient, fast, convenient and versatile POM coupling method.

引用

页码：19059 / 19062

页数：4

共 2 条

[1] A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids
Yang, Hai-Kuan
Zhao, Hong
Wang, Xiao-Min
Li, Yan-Kun
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 538 : 711 - 719
[2] Post-Functionalization of an Anderson-Type Polyoxomolybdate Using a Metal-Free Diels-Alder Click Reaction
Yang, Hai-Kuan
Su, Ming-Ming
Ren, Li-Jun
Tang, Jing
Yan, Yu-Kun
Miao, Wen-Ke
Zheng, Ping
Wang, Wei
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (08) : 1381 - 1389

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