Synthesis of cobalt on cobalt-aluminate via solvothermal method and its catalytic properties for carbon monoxide hydrogenation

被引：19

作者：

Rojanapipatkul, Sidrat ^{[1
]}

Jongsomjit, Bunjerd ^{[1
]}

机构：

[1] Chulalongkorn Univ, Dept Chem Engn, Fac Engn, Ctr Excellence Catalysis & Catalyt React Engn, Bangkok 10330, Thailand

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 10卷 / 02期

关键词：

Cobalt-aluminate; Cobalt catalyst; CO hydrogenation; Solvothermal; Alumina;

D O I：

10.1016/j.catcom.2008.08.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The study focused on synthesis of cobalt on cobalt-aluminate catalyst in one-pot via the solvothermal process. The obtained catalysts apparently exhibited higher activities than that prepared from the conventional solvothermal-derived alumina-supported cobalt catalyst without any changes in product selectivity during methanation. Enhanced activities can be attributed to the smaller amount of non-reducible cobalt-aluminate formed (at temperature <800 degrees C. Increased Co/Al molar ratios (1.0 and 2.0) also resulted in increased activities whereas the holding time during solvothermal synthesis had only little effect. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：232 / 236

页数：5

共 17 条

[1] ON THE MECHANISM OF THE FISCHER-TROPSCH REACTION - THE CHAIN PROPAGATION STEP [J].