Mesitylcopper - A Powerful Tool in Synthetic Chemistry

被引：76

作者：

Stollenz, Michael ^{[1
]}

Meyer, Franc ^{[2
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 22期

关键词：

MONOMERIC BIS(ETA(2)-ALKYNE) COMPLEXES; POLYNUCLEAR ARYL DERIVATIVES; N-HETEROCYCLIC CARBENE; RAY CRYSTAL-STRUCTURE; X-RAY; STRUCTURAL-CHARACTERIZATION; COPPER(I) COMPLEXES; CONJUGATE ADDITION; BETA-DIKETIMINATE; SOLID-STATE;

D O I：

10.1021/om3007689

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Since its first report in 1981, mesitylcopper has become an extremely popular and useful reagent, with many new applications emerging during the past decade. This review summarizes its structural and spectroscopic properties and gives a brief overview of the multitude of fascinating compounds and reactions that have been discovered by using mesitylcopper. Specifically, the role of mesitylcopper in synthesizing oligonuclear homo- and heteroleptic copper(I) frameworks, including biorelevant copper(I) complexes, and the application of mesitylcopper in stoichiometric and catalytic C-C and C-heteroatom bond-forming reactions and as a precursor for nanoparticles and intermetallic phases are covered.

引用

页码：7708 / 7727

页数：20

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