Transfer hydrogenation of nitro compounds with heteropolyacid catalysts

被引：15
作者：
Joshi, MV
Mukesh, D
机构：
[1] ICI India Research and Technology Centre, Thane 400 601, Maharashtra, Thane-Belapur Road
来源：
JOURNAL OF CATALYSIS | 1997年 / 168卷 / 02期
关键词：
D O I：
10.1006/jcat.1997.1619
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
12-Molybdophosphoric acid-catalyzed transfer hydrogenation of nitroaromatics in homogeneous phase under mild conditions with hydrazine as hydrogen donor is described. Lower yields were observed with ortho- and meta-substituted than with para-substituted nitrobenzenes. IR, ESR, NMR, and X-ray photoelectron studies indicated that Mo6+ is reduced to Mo5+, which is the active species, and coordinates with the electron-deficient nitro compound; in the process Mo5+ is reoxidized. (C) 1997 Academic Press.
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页码：273 / 277
页数：5
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