Sorption and desorption of Pb2+ ions by dead Sargassum sp biomass

被引:147
作者
Martins, BL [1 ]
Cruz, CCV [1 ]
Luna, AS [1 ]
Henriques, CA [1 ]
机构
[1] Univ Estado Rio De Janeiro, Dept Analyt Chem, Inst Chem, BR-20559900 Rio De Janeiro, Brazil
关键词
biosorption; equilibrium; kinetic; lead; Sargassum sp;
D O I
10.1016/j.bej.2005.08.007
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Dead Sargassum sp. as a biosorbent for Pb2+ ions from aqueous solutions was studied. Kinetics and equilibrium of Pb2+ biosorption were evaluated. The biosorption process used in this work followed a second-order kinetics and was not influenced by temperature, at least within 298-328 K. The equilibrium of biosorption was well described by Langmuir isotherm and the maximum Pb2+ uptake capacity (1.26 mmol g(-1)) is higher than those reported in the literature, for different sorbents. More than 95% of sorbed Pb2+ cations could be removed by desorption with a 0.10 mol l(-1) Na(2)EDTA solution at 298 K. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:310 / 314
页数:5
相关论文
共 18 条
[1]   Cadmium removal from aqueous solutions by chitin: kinetic and equilibrium studies [J].
Benguella, B ;
Benaissa, H .
WATER RESEARCH, 2002, 36 (10) :2463-2474
[2]   Biosorption of lead, copper and cadmium by biomass of Pseudomonas aeruginosa PU21 [J].
Chang, JS ;
Law, R ;
Chang, CC .
WATER RESEARCH, 1997, 31 (07) :1651-1658
[3]   HEAVY-METAL BIOSORPTION BY FUNGAL MYCELIAL BY-PRODUCTS - MECHANISMS AND INFLUENCE OF PH [J].
FOUREST, E ;
ROUX, JC .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 1992, 37 (03) :399-403
[4]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[5]   The viral transmembrane superfamily: Possible divergence of Arenavirus and Filovirus glycoproteins from a common RNA virus ancestor [J].
Gallaher W.R. ;
DiSimone C. ;
Buchmeier M.J. .
BMC Microbiology, 1 (1) :1-6
[6]   The sorption of lead(II) ions on peat [J].
Ho, YS ;
McKay, G .
WATER RESEARCH, 1999, 33 (02) :578-584
[7]   Pseudo-second order model for sorption processes [J].
Ho, YS ;
McKay, G .
PROCESS BIOCHEMISTRY, 1999, 34 (05) :451-465
[8]   Removal and recovery of lead using nonliving biomass of marine algae [J].
Jalali, R ;
Ghafourian, H ;
Asef, Y ;
Davarpanah, SJ ;
Sepehr, S .
JOURNAL OF HAZARDOUS MATERIALS, 2002, 92 (03) :253-262
[9]  
Lagergren S., 1907, K. Sven. Vetenskad. Handl, V2, DOI 10.1007/BF01501332
[10]   THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. [J].
Langmuir, Irving .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1918, 40 :1361-1403