Dehydrogenation and condensation in catalytic conversion of iso-propanol over CuO/MgO system doped with Li2O and ZrO2

被引:31
作者
El-Molla, SA [1 ]
机构
[1] Ain Shams Univ, Dept Chem, Fac Educ, Cairo 11757, Egypt
关键词
CuO/MgO catalyst; ZrO2- and Li2O-doping; iso-propanol conversion; MIBK;
D O I
10.1016/j.apcata.2005.09.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of Li2O and ZrO2-doping on the surface and catalytic properties of CuO/MgO system have been investigated. The dopant concentration was changed between 0.6 and 3.6 mol% Li2O and that of ZrO2 between 2.4-7.7 mol%. Pure and variously doped solids were calcined at 673 and 773 K. The techniques employed for characterization of different solids were XRD, nitrogen adsorption at 77 K and catalytic conversion of iso-propanol at different reaction temperatures ranged between 423 and 573 K. The results revealed that the addition increasing amounts of dopant (Li2O and ZrO2) to CuO/MgO Solid led to an increase in the degree of dispersion of CuO phase and a decrease in the specific surface areas of the investigated solids. Li2O and ZrO2-doping increases the, catalytic conversion of iso-propanol, which proceeds mainly via dehydrogenation to give acetone and aldol condensation of the produced acetone to give methyl isobutyl ketone (MIBK). Doping with 1.2 mol% Li2O for the solids calcined at 673 K increases both of total conversion and selectivity to MIBK at reaction temperature 473 K with 24% and 25%, respectively. Doping with 7.7 mol% ZrO2 for the investigated solids calcined at 673 K increases both of total conversion and selectivity to MIBK at reaction temperature 473 K with 32% and 99%, respectively. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:103 / 108
页数:6
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