New procedures for arsenic speciation: A review

被引：80
作者：
Chen, Ming-Li [1 ]
Ma, Lin-Yu [1 ]
Chen, Xu-Wei [1 ]
机构：
[1] Northeastern Univ, Coll Sci, Res Ctr Analyt Sci, Shenyang 110819, Peoples R China
来源：
TALANTA | 2014年 / 125卷
关键词：
Arsenic speciation; Sample pretreatment; Preconcentration/separation; Review; PLASMA-MASS SPECTROMETRY; ATOMIC-ABSORPTION-SPECTROMETRY; MICROWAVE-ASSISTED EXTRACTION; CAPILLARY-ELECTROPHORESIS; ICP-MS; SEPARATION; WATER; EXCHANGE; SAMPLES; PRECONCENTRATION;
D O I：
10.1016/j.talanta.2014.02.037
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Considerable analytical methods have been developed for arsenic speciation in the last 5 years, the details of these new arsenic speciation procedures are thus summarized in present mini review. The performances of various sample pretreatment techniques including solid phase extraction, liquid-liquid extraction, hydride generation, liquid chromatography and capillary electrophoresis, which offer effective preconcentration/separation and eventually contribute greatly to excellent sensitivity and selectivity in arsenic speciation when coupling with suitable detection mode, are discussed and compared thoroughly. High-performance liquid chromatography coupling with inductively coupled plasma mass spectrometry and hydride generation atomic spectrometry are proved to be the most powerful hyphenated methodologies for arsenic speciation in environmental and biological matrices. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：78 / 86
页数：9
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