Polymer-supercritical fluid interactions

被引:86
作者
Kikic, I. [1 ]
机构
[1] Univ Trieste, DICAMP, I-34127 Trieste, Italy
关键词
Polymers; Supercritical CO2; Sorption; Thermodynamic models; EQUATION-OF-STATE; GLASS-TRANSITION TEMPERATURE; PRESSURE PHASE-EQUILIBRIA; CARBON-DIOXIDE; POLY(METHYL METHACRYLATE); SEMICRYSTALLINE POLYMERS; MOLECULAR INTERPRETATION; PERTURBATION-THEORY; FOAMING AGENT; IN-SITU;
D O I
10.1016/j.supflu.2008.10.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The role of the interactions in systems containing polymers for the definition of operative conditions in the supercritical fluid processing is reviewed. The approaches used for the study of the behaviour of polymers in presence of supercritical fluids are considered also in the case of mixtures containing more than two components. The attention is focused mainly on the thermodynamic properties of the systems. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:458 / 465
页数:8
相关论文
共 92 条
[1]   Plasticization of polymers with supercritical carbon dioxide: Experimental determination of glass-transition temperatures [J].
Alessi, P ;
Cortesi, A ;
Kikic, I ;
Vecchione, F .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (09) :2189-2193
[2]   Modeling the phase behavior of commercial biodegradable polymers and copolymer in supercritical fluids [J].
Arce, P ;
Aznar, M .
FLUID PHASE EQUILIBRIA, 2005, 238 (02) :242-253
[3]   Solubility of carbon dioxide in polymers by the quartz crystal microbalance technique [J].
Aubert, JH .
JOURNAL OF SUPERCRITICAL FLUIDS, 1998, 11 (03) :163-172
[4]   A comparison of analytic thermodynamic models for gas solubility, volume dilation and heat of sorption in glassy polymeric materials [J].
Banerjee, T ;
Lipscomb, GG .
COMPUTATIONAL AND THEORETICAL POLYMER SCIENCE, 2000, 10 (05) :437-445
[5]   SORPTION AND DIFFUSION IN ETHYL CELLULOSE .3. COMPARISON BETWEEN ETHYL CELLULOSE AND RUBBER [J].
BARRER, RM ;
BARRIE, JA ;
SLATER, J .
JOURNAL OF POLYMER SCIENCE, 1958, 27 (115) :177-197
[6]   Solubility in glassy polymers: Correlations through the nonequilibrium lattice fluid model [J].
Baschetti, MG ;
Doghieri, F ;
Sarti, GC .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (14) :3027-3037
[7]   Sorption and swelling of semicrystalline polymers in supercritical CO2 [J].
Bonavoglia, B ;
Storti, G ;
Morbidelli, M ;
Rajendran, A ;
Mazzotti, M .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2006, 44 (11) :1531-1546
[8]   A group contribution estimation of the thermodynamic properties of polymers [J].
Boudouris, D ;
Constantinou, L ;
Panayiotou, C .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (09) :3968-3973
[9]   Maturation of a ketoprofen/β-cyclodextrin mixture with supercritical carbon dioxide [J].
Bounaceur, Arezki ;
Rodier, Elisabeth ;
Fages, Jacques .
JOURNAL OF SUPERCRITICAL FLUIDS, 2007, 41 (03) :429-439
[10]   Supercritical solvent impregnation of ophthalmic drugs on chitosan derivatives [J].
Braga, Mara E. M. ;
Pato, Maria T. Vaz ;
Costa Silva, Helio S. R. ;
Ferreira, Elisabeth I. ;
Gil, Maria H. ;
Duarte, Catarina M. M. ;
de Sousa, Herminio C. .
JOURNAL OF SUPERCRITICAL FLUIDS, 2008, 44 (02) :245-257